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全溶液处理的 n-i-p 型钙钛矿太阳能电池具有平面结：电荷提取层如何决定开路电压。

Fully Solution-Processed n-i-p-Like Perovskite Solar Cells with Planar Junction: How the Charge Extracting Layer Determines the Open-Circuit Voltage.

机构信息

Center for Nano Science and Technology @Polimi, Istituto Italiano di Tecnologia, via Giovanni Pascoli 70/3, 20133, Milan, Italy.

Dipartimento di Chimica, Materiali e Ing. Chimica "G. Natta,", Politecnico di Milano, Piazza L. Da Vinci 32, 20133, Milano, Italy.

出版信息

Adv Mater. 2017 Apr;29(15). doi: 10.1002/adma.201604493. Epub 2017 Jan 23.

DOI:10.1002/adma.201604493
PMID:28112839
Abstract

Fully solution-processed direct perovskite solar cells with a planar junction are realized by incorporating a cross-linked [6,6]-phenyl-C61-butyric styryl dendron ester layer as an electron extracting layer. Power conversion efficiencies close to 19% and an open-circuit voltage exceeding 1.1 V with negligible hysteresis are delivered. A perovskite film with superb optoelectronic qualities is grown, which reduces carrier recombination losses and hence increases V .

摘要

通过引入交联[6,6]-苯基-C61-丁酸芴酯作为电子提取层，实现了具有平面结的全溶液处理直接钙钛矿太阳能电池。该器件实现了接近 19%的功率转换效率和超过 1.1V 的开路电压，且几乎没有滞后现象。所制备的钙钛矿薄膜具有优异的光电性能，降低了载流子复合损耗，从而提高了 VOC。

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