Center for Programmable Materials, School of Materials Science and Engineering, Nanyang Technological University , 50 Nanyang Avenue, Singapore 639798, Singapore.
College of Materials Science and Engineering, Zhejiang University of Technology , 18 Chaowang Road, Hangzhou 310014, China.
Chem Rev. 2017 May 10;117(9):6225-6331. doi: 10.1021/acs.chemrev.6b00558. Epub 2017 Mar 17.
Since the discovery of mechanically exfoliated graphene in 2004, research on ultrathin two-dimensional (2D) nanomaterials has grown exponentially in the fields of condensed matter physics, material science, chemistry, and nanotechnology. Highlighting their compelling physical, chemical, electronic, and optical properties, as well as their various potential applications, in this Review, we summarize the state-of-art progress on the ultrathin 2D nanomaterials with a particular emphasis on their recent advances. First, we introduce the unique advances on ultrathin 2D nanomaterials, followed by the description of their composition and crystal structures. The assortments of their synthetic methods are then summarized, including insights on their advantages and limitations, alongside some recommendations on suitable characterization techniques. We also discuss in detail the utilization of these ultrathin 2D nanomaterials for wide ranges of potential applications among the electronics/optoelectronics, electrocatalysis, batteries, supercapacitors, solar cells, photocatalysis, and sensing platforms. Finally, the challenges and outlooks in this promising field are featured on the basis of its current development.
自 2004 年机械剥离石墨烯以来,凝聚态物理、材料科学、化学和纳米技术等领域对超薄二维(2D)纳米材料的研究呈指数级增长。本综述重点介绍了超薄 2D 纳米材料的最新进展,突出了其引人注目的物理、化学、电子和光学特性及其各种潜在应用。首先,我们介绍了超薄 2D 纳米材料的独特进展,然后描述了它们的组成和晶体结构。随后总结了它们的各种合成方法,包括对它们优缺点的深入了解,并就合适的表征技术提出了一些建议。我们还详细讨论了这些超薄 2D 纳米材料在电子/光电、电催化、电池、超级电容器、太阳能电池、光催化和传感平台等广泛潜在应用中的利用。最后,根据当前的发展情况,介绍了该有前途的领域所面临的挑战和展望。