Institute of Physical Chemistry, Polish Academy of Sciences, Kasprzaka 44/52, 01-224, Warsaw, Poland.
Institut de Chimie des Milieux et Matériaux de Poitiers (IC2MP), Université de Poitiers, CNRS, ENSIP, B1, 1 rue Marcel Doré, 86073, Poitiers Cedex 9, France.
Top Curr Chem (Cham). 2017 Apr;375(2):41. doi: 10.1007/s41061-017-0122-y. Epub 2017 Mar 23.
Lignocellulosic biomass represents a natural renewable chemical feedstock that can be used to produce high value-added chemicals and platform molecules. Nowadays, there are extensive studies on a variety of aspects concerning the valorization of lignocellulosic biomass into desirable products. Among the current technologies for biomass conversion some require extreme conditions along with high temperatures and pressures. Therefore, major technological innovations based on more economical and environmental methodologies are currently developed both in academic laboratories and in industry. In this context, ultrasound-assisted catalysis constitutes an alternative method offering new strategies to upgrade biomass. The possibility of combining catalysis with sonication indeed provides avenues that are worth exploring for the valorization of lignocellulosic compounds into value-added chemical feedstocks. In this mini-review, the available sonochemical systems are first presented, with a focus on the most important ultrasonic parameters, which is intended to provide a mechanistic background. Next, this contribution aims to provide insight into the most recent developments along with prominent examples in the field of sonocatalysis applied to the chemical transformation of lignocellulosic biomass and its derivatives.
木质纤维素生物质代表了一种天然可再生的化学原料,可以用于生产高附加值的化学品和平台分子。如今,对于将木质纤维素生物质转化为理想产品的各种方面,有广泛的研究。在生物质转化的现有技术中,有些需要极端条件,伴随着高温和高压。因此,目前在学术实验室和工业中都在开发基于更经济和环保方法的重大技术创新。在这种情况下,超声辅助催化构成了一种替代方法,为生物质的升级提供了新的策略。将催化与超声结合的可能性确实为将木质纤维素化合物转化为高附加值的化学原料提供了值得探索的途径。在这篇小型综述中,首先介绍了现有的声化学系统,重点介绍了最重要的超声参数,旨在提供一个机械背景。接下来,本研究旨在深入了解声催化领域的最新发展以及该领域在应用于木质纤维素生物质及其衍生物的化学转化方面的突出实例。