以分子氧作为唯一氧化剂，钯催化尿嘧啶和咖啡因的C-H烯基化反应。
Palladium-catalyzed C-H olefination of uracils and caffeines using molecular oxygen as the sole oxidant.
作者信息
Zhang Xinyu, Su Lv, Qiu Lin, Fan Zhenwei, Zhang Xiaofeng, Lin Shen, Huang Qiufeng
机构信息
College of Chemistry & Chemical Engineering, Fujian Normal University, Fuzhou 350007, People's Republic of China.
出版信息
Org Biomol Chem. 2017 Apr 18;15(16):3499-3506. doi: 10.1039/c7ob00616k.
PMID:28387403
Abstract
The palladium-catalyzed oxidative C-H olefination of uracils or caffeines with alkenes using an atmospheric pressure of molecular oxygen as the sole oxidant has been disclosed. This novel strategy offers an efficient and environmentally friendly method to biologically important C5-alkene uracil derivatives or C8-alkene caffeine derivatives.
摘要
已公开了使用大气压分子氧作为唯一氧化剂，钯催化尿嘧啶或咖啡因与烯烃的氧化C-H烯基化反应。这种新策略为合成具有生物学重要性的C5-烯烃尿嘧啶衍生物或C8-烯烃咖啡因衍生物提供了一种高效且环境友好的方法。
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