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氧化石墨烯增强二苯基丙氨酸纳米复合材料的热稳定性和水稳定性提升

Thermal and aqueous stability improvement of graphene oxide enhanced diphenylalanine nanocomposites.

作者信息

Ryan Kate, Neumayer Sabine M, Maraka Harsha Vardhan R, Buchete Nicolae-Viorel, Kholkin Andrei L, Rice James H, Rodriguez Brian J

机构信息

School of Physics, University College Dublin, Dublin, Ireland.

Conway Institute of Biomolecular and Biomedical Research, University College Dublin, Dublin, Ireland.

出版信息

Sci Technol Adv Mater. 2017 Feb 23;18(1):172-179. doi: 10.1080/14686996.2016.1277504. eCollection 2017.

Abstract

Nanocomposites of diphenylalanine (FF) and carbon based materials provide an opportunity to overcome drawbacks associated with using FF micro- and nanostructures in nanobiotechnology applications, in particular their poor structural stability in liquid solutions. In this study, FF/graphene oxide (GO) composites were found to self-assemble into layered micro- and nanostructures, which exhibited improved thermal and aqueous stability. Dependent on the FF/GO ratio, the solubility of these structures was reduced to 35.65% after 30 min as compared to 92.4% for pure FF samples. Such functional nanocomposites may extend the use of FF structures to e.g. biosensing, electrochemical, electromechanical or electronic applications.

摘要

二苯基丙氨酸(FF)与碳基材料的纳米复合材料为克服在纳米生物技术应用中使用FF微米和纳米结构所带来的缺点提供了契机,尤其是其在液体溶液中较差的结构稳定性。在本研究中,发现FF/氧化石墨烯(GO)复合材料能自组装成层状微米和纳米结构,这些结构表现出更好的热稳定性和水稳定性。取决于FF/GO的比例,这些结构在30分钟后的溶解度降至35.65%,而纯FF样品为92.4%。这种功能性纳米复合材料可能会将FF结构的应用扩展到例如生物传感、电化学、机电或电子应用等领域。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a3d0/5402763/1e787f9fc0d5/tsta_a_1277504_uf0001_oc.jpg

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