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TiO 和 BFCO 薄膜的磁控溅射和脉冲激光沉积联合制备。

Combined magnetron sputtering and pulsed laser deposition of TiO and BFCO thin films.

机构信息

INRS Centre for Energy, Materials and Telecommunications, 1650 Boul. Lionel Boulet, J3X 1S2, Varennes, QC, Canada.

Plasmionique Inc., 1650 Boul. Lionel Boulet, J3X 1S2, Varennes, QC, Canada.

出版信息

Sci Rep. 2017 May 31;7(1):2503. doi: 10.1038/s41598-017-02284-0.

Abstract

We report the successful demonstration of a hybrid system that combines pulsed laser deposition (PLD) and magnetron sputtering (MS) to deposit high quality thin films. The PLD and MS simultaneously use the same target, leading to an enhanced deposition rate. The performance of this technique is demonstrated through the deposition of titanium dioxide and bismuth-based perovskite oxide BiFeCrO (BFCO) thin films on Si(100) and LaAlO (LAO) (100). These specific oxides were chosen due to their functionalities, such as multiferroic and photovoltaic properties (BFCO) and photocatalysis (TiO). We compare films deposited by conventional PLD, MS and PLD combined with MS, and show that under all conditions the latter technique offers an increased deposition rate (+50%) and produces films denser (+20%) than those produced by MS or PLD alone, and without the large clusters found in the PLD-deposited films. Under optimized conditions, the hybrid technique produces films that are two times smoother than either technique alone.

摘要

我们成功展示了一种将脉冲激光沉积(PLD)和磁控溅射(MS)相结合的混合系统,用于沉积高质量的薄膜。PLD 和 MS 同时使用同一个靶材,从而提高了沉积速率。通过在 Si(100) 和 LaAlO(LAO)(100) 上沉积二氧化钛和基于铋的钙钛矿氧化物 BiFeCrO (BFCO) 薄膜,证明了该技术的性能。选择这些特定的氧化物是因为它们具有多功能铁电和光伏特性(BFCO)和光催化(TiO)。我们比较了由传统 PLD、MS 和 PLD 与 MS 组合沉积的薄膜,并表明在所有条件下,后一种技术提供了更高的沉积速率(+50%)和更高的密度(+20%),比单独使用 MS 或 PLD 沉积的薄膜更高,并且没有 PLD 沉积的薄膜中发现的大团簇。在优化条件下,混合技术产生的薄膜比单独使用任何一种技术都要光滑两倍。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/051f/5451404/1a8ba7f8e3ae/41598_2017_2284_Fig1_HTML.jpg

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