利用三氟甲亚磺酸盐无过渡金属合成β-三氟甲基烯胺
Transition-metal-free synthesis of β-trifluoromethylated enamines with trifluoromethanesulfinate.
作者信息
Jiang Huanfeng, Huang Wei, Yu Yue, Yi Songjian, Li Jiawei, Wu Wanqing
机构信息
Key Laboratory of Functional Molecular Engineering of Guangdong Province, School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou 510640, China.
出版信息
Chem Commun (Camb). 2017 Jul 4;53(54):7473-7476. doi: 10.1039/c7cc03125d.
PMID:28642954
Abstract
We have developed a transition-metal free trifluoromethylation protocol between enamines and CFSONa. A wide range of β-trifluoromethyl substituted enamines were delivered in moderate to high yields with only E-configurations.
摘要
我们已经开发出一种在烯胺与CFSONa之间进行的无过渡金属三氟甲基化反应方案。一系列β-三氟甲基取代的烯胺以中等至高产率得到，且仅具有E-构型。
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