Cooper Andrew I
Department of Chemistry and Materials Innovation Factory, Leverhulme Centre for Functional Materials Design, University of Liverpool, 51 Oxford Street, Liverpool, L7 3NY, United Kingdom.
ACS Cent Sci. 2017 Jun 28;3(6):544-553. doi: 10.1021/acscentsci.7b00146. Epub 2017 May 18.
Until recently, porous molecular solids were isolated curiosities with properties that were eclipsed by porous frameworks, such as metal-organic frameworks. Now molecules have emerged as a functional materials platform that can have high levels of porosity, good chemical stability, and, uniquely, solution processability. The lack of intermolecular bonding in these materials has also led to new, counterintuitive states of matter, such as porous liquids. Our ability to design these materials has improved significantly due to advances in computational prediction methods.
直到最近，多孔分子固体仍是孤立的奇特物质，其性能被多孔框架材料（如金属有机框架材料）所掩盖。如今，分子已成为一种功能材料平台，具有高度的孔隙率、良好的化学稳定性，且独特之处在于具有溶液可加工性。这些材料中分子间键合的缺乏还导致了新的、违反直觉的物质状态，如多孔液体。由于计算预测方法的进步，我们设计这些材料的能力有了显著提高。
