Department of Chemistry, Jilin University , Changchun 130012, People's Republic of China.
Department of Chemistry, Lancaster University , Lancaster LA1 4YB, United Kingdom.
Chem Rev. 2017 Feb 8;117(3):1515-1563. doi: 10.1021/acs.chemrev.6b00439. Epub 2016 Dec 30.
Porous organic materials have garnered colossal interest with the scientific fraternity due to their excellent gas sorption performances, catalytic abilities, energy storage capacities, and other intriguing applications. This review encompasses the recent significant breakthroughs and the conventional functions and practices in the field of porous organic materials to find useful applications and imparts a comprehensive understanding of the strategic evolution of the design and synthetic approaches of porous organic materials with tunable characteristics. We present an exhaustive analysis of the design strategies with special emphasis on the topologies of crystalline and amorphous porous organic materials. In addition to elucidating the structure-function correlation and state-of-the-art applications of porous organic materials, we address the challenges and restrictions that prevent us from realizing porous organic materials with tailored structures and properties for useful applications.
多孔有机材料因其优异的气体吸附性能、催化能力、储能能力和其他有趣的应用而引起了科学界的极大兴趣。本综述涵盖了多孔有机材料领域最近的重大突破以及传统功能和实践，以寻找有用的应用，并全面了解具有可调特性的多孔有机材料的设计和合成方法的战略演变。我们对设计策略进行了详尽的分析，特别强调了结晶和无定形多孔有机材料的拓扑结构。除了阐明多孔有机材料的结构-功能关系和最新应用外，我们还讨论了阻碍我们实现具有定制结构和性能的多孔有机材料以用于有用应用的挑战和限制。
