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飞秒研究:观测过渡态及其他超短寿命物种。

Femtosecond studies: observing transition states and other ultra-short-lived species.

作者信息

Kemp Terence J

出版信息

Sci Prog. 2016 Jun 1;99(2):133-152. doi: 10.3184/003685016X14616057013539.

Abstract

To celebrate 2015 as the 'International Year of Light', this article offers a short survey of the progress made since the award of the Nobel Prize of 1999 to Professor Ahmed Zewail for his pioneering work on taking the timescale for observation of light-induced events down to the femtosecond level. Developments have included the extension of studies (i) to larger molecules, leading up to biological systems; (ii) the increased range of detection methods of transient species from the UV-Vis to the infrared region; (iii) the introduction of Raman spectroscopy to augment IR studies; (iv) examination of combination events to supplement dissociation events; (v) the interrogation of transient structures by X-ray absorption spectroscopy; (vi) the study of reactions taking place at solid surfaces.

摘要

为庆祝2015年成为“国际光年”,本文简要回顾了自1999年艾哈迈德·泽维尔教授因其在将光致事件的观测时间尺度降至飞秒级别的开创性工作而获得诺贝尔奖以来所取得的进展。这些进展包括:(i) 将研究扩展到更大的分子,直至生物系统;(ii) 瞬态物种的检测方法范围从紫外-可见区域扩展到红外区域;(iii) 引入拉曼光谱以增强红外研究;(iv) 研究复合事件以补充解离事件;(v) 通过X射线吸收光谱法探究瞬态结构;(vi) 研究在固体表面发生的反应。

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本文引用的文献

1
Ultrafast excited-state processes in inorganic systems.
Acc Chem Res. 2015 May 19;48(5):1207-8. doi: 10.1021/acs.accounts.5b00235.
2
Electron injection dynamics in high-potential porphyrin photoanodes.
Acc Chem Res. 2015 May 19;48(5):1423-31. doi: 10.1021/ar500363q. Epub 2015 May 4.
3
Fe(II)-Polypyridines as Chromophores in Dye-Sensitized Solar Cells: A Computational Perspective.
Acc Chem Res. 2015 May 19;48(5):1441-9. doi: 10.1021/ar500428t. Epub 2015 Apr 28.
4
Solvation-driven charge transfer and localization in metal complexes.
Acc Chem Res. 2015 May 19;48(5):1432-40. doi: 10.1021/ar5003939. Epub 2015 Apr 22.
5
Dynamics of rhenium photocatalysts revealed through ultrafast multidimensional spectroscopy.
Acc Chem Res. 2015 Apr 21;48(4):1123-30. doi: 10.1021/ar500402r. Epub 2015 Apr 3.
6
Probing and Exploiting the Interplay between Nuclear and Electronic Motion in Charge Transfer Processes.
Acc Chem Res. 2015 Apr 21;48(4):1131-9. doi: 10.1021/ar500420c. Epub 2015 Mar 19.
7
Mechanistic studies of photoinduced spin crossover and electron transfer in inorganic complexes.
Acc Chem Res. 2015 Apr 21;48(4):1140-8. doi: 10.1021/ar500407p. Epub 2015 Mar 19.
8
Excited state dynamics and isomerization in ruthenium sulfoxide complexes.
Acc Chem Res. 2015 Apr 21;48(4):1115-22. doi: 10.1021/ar500396a. Epub 2015 Mar 11.
9
Energy cascades, excited state dynamics, and photochemistry in cob(III)alamins and ferric porphyrins.
Acc Chem Res. 2015 Mar 17;48(3):860-7. doi: 10.1021/ar5004016. Epub 2015 Mar 5.
10
Surface chemistry. Probing the transition state region in catalytic CO oxidation on Ru.
Science. 2015 Feb 27;347(6225):978-82. doi: 10.1126/science.1261747. Epub 2015 Feb 12.

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