Kemp Terence J
Sci Prog. 2016 Jun 1;99(2):133-152. doi: 10.3184/003685016X14616057013539.
To celebrate 2015 as the 'International Year of Light', this article offers a short survey of the progress made since the award of the Nobel Prize of 1999 to Professor Ahmed Zewail for his pioneering work on taking the timescale for observation of light-induced events down to the femtosecond level. Developments have included the extension of studies (i) to larger molecules, leading up to biological systems; (ii) the increased range of detection methods of transient species from the UV-Vis to the infrared region; (iii) the introduction of Raman spectroscopy to augment IR studies; (iv) examination of combination events to supplement dissociation events; (v) the interrogation of transient structures by X-ray absorption spectroscopy; (vi) the study of reactions taking place at solid surfaces.
为庆祝2015年成为“国际光年”,本文简要回顾了自1999年艾哈迈德·泽维尔教授因其在将光致事件的观测时间尺度降至飞秒级别的开创性工作而获得诺贝尔奖以来所取得的进展。这些进展包括:(i) 将研究扩展到更大的分子,直至生物系统;(ii) 瞬态物种的检测方法范围从紫外-可见区域扩展到红外区域;(iii) 引入拉曼光谱以增强红外研究;(iv) 研究复合事件以补充解离事件;(v) 通过X射线吸收光谱法探究瞬态结构;(vi) 研究在固体表面发生的反应。