Center for Photonics and Nanoelectronics, Department of Electrical and Computer Engineering, Lehigh University, Bethlehem, PA, 18015, USA.
Department of Electrical and Computer Engineering, Clarkson University, Potsdam, NY, 13699, USA.
Sci Rep. 2017 Jul 27;7(1):6671. doi: 10.1038/s41598-017-06889-3.
The III-Nitride digital alloy (DA) is comprehensively studied as a short-period superlattice nanostructure consisting of ultra-thin III-Nitride epitaxial layers. By stacking the ultra-thin III-Nitride epitaxial layers periodically, these nanostructures are expected to have comparable optoelectronic properties as the conventional III-Nitride alloys. Here we carried out numerical studies on the InGaN DA showing the tunable optoelectronic properties of the III-Nitride DA. Our study shows that the energy gap of the InGaN DA can be tuned from ~0.63 eV up to ~2.4 eV, where the thicknesses and the thickness ratio of each GaN and InN ultra-thin binary layers within the DA structure are the key factors for tuning bandgap. Correspondingly, the absorption spectra of the InGaN DA yield broad wavelength tunability which is comparable to that of bulk InGaN ternary alloy. In addition, our investigation also reveals that the electron-hole wavefunction overlaps are remarkably large in the InGaN DA structure despite the existence of strain effect and build-in polarization field. Our findings point out the potential of III-Nitride DA as an artificially engineered nanostructure for optoelectronic device applications.
III 族氮化物数字合金(DA)作为一种由超薄 III 族氮化物外延层组成的短周期超晶格纳米结构得到了全面研究。通过周期性地堆叠超薄 III 族氮化物外延层,这些纳米结构有望具有与传统 III 族氮化物合金相当的光电性能。在这里,我们对 InGaN DA 进行了数值研究,展示了 III 族氮化物 DA 的可调光电特性。我们的研究表明,InGaN DA 的能隙可以从0.63 eV 调谐到2.4 eV,其中 DA 结构中每个 GaN 和 InN 超薄二元层的厚度和厚度比是调谐能带隙的关键因素。相应地,InGaN DA 的吸收光谱产生了宽波长可调谐性,可与体 InGaN 三元合金相媲美。此外,我们的研究还表明,尽管存在应变效应和内置极化场,InGaN DA 结构中的电子-空穴波函数重叠非常大。我们的发现指出了 III 族氮化物 DA 作为一种用于光电设备应用的人工工程纳米结构的潜力。