文献检索文档翻译深度研究
Suppr Zotero 插件Zotero 插件
邀请有礼套餐&价格历史记录

新学期，新优惠

限时优惠:9月1日-9月22日

30天高级会员仅需29元

1天体验卡首发特惠仅需5.99元

了解详情
不再提醒
插件&应用
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
高级版
套餐订阅购买积分包
AI 工具
文献检索文档翻译深度研究
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2025

酰化木聚糖基磁性Fe₃O₄水凝胶的合成及其在H₂O₂检测中的应用。

Synthesis of Acylated Xylan-Based Magnetic Fe₃O₄ Hydrogels and Their Application for H₂O₂ Detection.

作者信息

Dai Qing-Qing, Ren Jun-Li, Peng Feng, Chen Xiao-Feng, Gao Cun-Dian, Sun Run-Cang

机构信息

State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China.

Beijing Key Laboratory of Lignocellulosic Chemistry, Beijing Forestry University, Beijing 100083, China.

出版信息

Materials (Basel). 2016 Aug 11;9(8):690. doi: 10.3390/ma9080690.

DOI:10.3390/ma9080690
PMID:28773811
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5512512/
Abstract

Acylated xylan-based magnetic Fe₃O₄ nanocomposite hydrogels (ACX-MNP-gels) were prepared by fabricating Fe₃O₄ nanoctahedra in situ within a hydrogel matrix which was synthesized by the copolymerization of acylated xylan (ACX) with acrylamide and -isopropylacrylamide under ultraviolet irradiation. The size of the Fe₃O₄ fabricated within the hydrogel matrix could be adjusted through controlling the crosslinking concentrations (C). The magnetic hydrogels showed desirable magnetic and mechanical properties, which were confirmed by XRD, Raman spectroscopy, physical property measurement system, SEM, TGA, and compression test. Moreover, the catalytic performance of the magnetic hydrogels was explored. The magnetic hydrogels (C = 7.5 wt %) presented excellent catalytic activity and provided a sensitive response to H₂O₂ detection even at a concentration level of 5 × 10 mol·L. This approach to preparing magnetic hydrogels loaded with Fe₃O₄ nanoparticles endows xylan-based hydrogels with new promising applications in biotechnology and environmental chemistry.

摘要

通过在水凝胶基质中原位制备八面体四氧化三铁（Fe₃O₄），制备了酰化木聚糖基磁性Fe₃O₄纳米复合水凝胶（ACX-MNP-凝胶）。该水凝胶基质是由酰化木聚糖（ACX）与丙烯酰胺和N-异丙基丙烯酰胺在紫外线照射下共聚合成的。通过控制交联浓度（C），可以调节水凝胶基质中制备的Fe₃O₄的尺寸。通过X射线衍射（XRD）、拉曼光谱、物理性能测量系统、扫描电子显微镜（SEM）、热重分析（TGA）和压缩试验证实，磁性水凝胶具有理想的磁性能和力学性能。此外，还探索了磁性水凝胶的催化性能。磁性水凝胶（C = 7.5 wt%）表现出优异的催化活性，即使在5×10⁻⁸mol·L的浓度水平下，对过氧化氢检测也能提供灵敏的响应。这种制备负载Fe₃O₄纳米颗粒的磁性水凝胶的方法，赋予了木聚糖基水凝胶在生物技术和环境化学领域新的应用前景。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/dc1a8a8ecd6b/materials-09-00690-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/f05fc90c391e/materials-09-00690-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/40932f97dc6f/materials-09-00690-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/45021245572f/materials-09-00690-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/d4d6dfada245/materials-09-00690-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/5f965c5b520d/materials-09-00690-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/56d50fc0e14b/materials-09-00690-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/3e4dc38cd28d/materials-09-00690-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/74ed96ab830f/materials-09-00690-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/7f450936d55f/materials-09-00690-g008a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/dc1a8a8ecd6b/materials-09-00690-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/f05fc90c391e/materials-09-00690-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/40932f97dc6f/materials-09-00690-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/45021245572f/materials-09-00690-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/d4d6dfada245/materials-09-00690-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/5f965c5b520d/materials-09-00690-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/56d50fc0e14b/materials-09-00690-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/3e4dc38cd28d/materials-09-00690-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/74ed96ab830f/materials-09-00690-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/7f450936d55f/materials-09-00690-g008a.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/76d1/5512512/dc1a8a8ecd6b/materials-09-00690-g009.jpg

相似文献

[1]
Synthesis of Acylated Xylan-Based Magnetic Fe₃O₄ Hydrogels and Their Application for H₂O₂ Detection.

Materials (Basel). 2016-8-11

[2]
Xylan-based temperature/pH sensitive hydrogels for drug controlled release.

Carbohydr Polym. 2016-5-24

[3]
Carbon Nanotubes Reinforced Maleic Anhydride-Modified Xylan-g-Poly(N-isopropylacrylamide) Hydrogel with Multifunctional Properties.

Materials (Basel). 2018-2-28

[4]
Physicochemical characteristics of Fe3O4 magnetic nanocomposites based on Poly(N-isopropylacrylamide) for anti-cancer drug delivery.

Asian Pac J Cancer Prev. 2014

[5]
Preparation of Fe₃O₄-Embedded Poly(styrene)/Poly(thiophene) Core/Shell Nanoparticles and Their Hydrogel Patterns for Sensor Applications.

Materials (Basel). 2014-1-2

[6]
Preparation of Xylan--/P(AA--AM)/GO Nanocomposite Hydrogel and its Adsorption for Heavy Metal Ions.

Polymers (Basel). 2019-4-4

[7]
Embedding magnetic nanoparticles into polysaccharide-based hydrogels for magnetically assisted bioseparation.

Chemphyschem. 2007-11-12

[8]
Smart pH/magnetic sensitive Hericium erinaceus residue carboxymethyl chitin/FeO nanocomposite hydrogels with adjustable characteristics.

Carbohydr Polym. 2020-6-16

[9]
Xylan-Based Hydrogels as a Potential Carrier for Drug Delivery: Effect of Pore-Forming Agents.

Pharmaceutics. 2018-12-5

[10]
Surface Morphology at the Microscopic Scale, Swelling/Deswelling, and the Magnetic Properties of PNIPAM/CMC and PNIPAM/CMC/Fe₃O₄ Hydrogels.

Gels. 2016-12-13

引用本文的文献

[1]
Magnetic Nanoparticle Composites: Synergistic Effects and Applications.

Adv Sci (Weinh). 2021-6

[2]
Carbon Nanotubes Reinforced Maleic Anhydride-Modified Xylan-g-Poly(N-isopropylacrylamide) Hydrogel with Multifunctional Properties.

Materials (Basel). 2018-2-28

本文引用的文献

[1]
Homogeneous acylation of xylan with 3,5-dinitrobenzoyl in ionic liquid and the adsorption property.

Carbohydr Polym. 2015-4-15

[2]
Preparation and adsorption property of xylan/poly(acrylic acid) magnetic nanocomposite hydrogel adsorbent.

Carbohydr Polym. 2014-11-15

[3]
Multi-responsive cellulose nanocrystal-rhodamine conjugates: an advanced structure study by solid-state dynamic nuclear polarization (DNP) NMR.

Phys Chem Chem Phys. 2014-12-21

[4]
Multiresponsive hydrogels based on xylan-type hemicelluloses and photoisomerized azobenzene copolymer as drug delivery carrier.

J Agric Food Chem. 2014-10-15

[5]
Photothermal poly(N-isopropylacrylamide)/Fe3O4 nanocomposite hydrogel as a movable position heating source under remote control.

Small. 2014-3-27

[6]
Dynamics of a thermo-responsive microgel colloid near to the glass transition.

J Chem Phys. 2014-2-7

[7]
High strength of hemicelluloses based hydrogels by freeze/thaw technique.

Carbohydr Polym. 2013-9-12

[8]
Preparation of xylan citrate--a potential adsorbent for industrial wastewater treatment.

Carbohydr Polym. 2012-12-3

[9]
Highly effective adsorption of heavy metal ions from aqueous solutions by macroporous xylan-rich hemicelluloses-based hydrogel.

J Agric Food Chem. 2012-4-6

[10]
Preparation of thermoresponsive and pH-sensitivity polymer magnetic hydrogel nanospheres as anticancer drug carriers.

Colloids Surf B Biointerfaces. 2011-7-30

文献AI研究员

20分钟写一篇综述，助力文献阅读效率提升50倍

立即体验

用中文搜PubMed

大模型驱动的PubMed中文搜索引擎

马上搜索

推荐工具

医学文档翻译智能文献检索