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氧化石墨烯的连续表面改性对冰核形成的影响。

Impact of sequential surface-modification of graphene oxide on ice nucleation.

作者信息

Biggs Caroline I, Packer Christopher, Hindmarsh Steven, Walker Marc, Wilson Neil R, Rourke Jonathan P, Gibson Matthew I

机构信息

Department of Chemistry, University of Warwick, Coventry, CV4 7AL, UK.

出版信息

Phys Chem Chem Phys. 2017 Aug 23;19(33):21929-21932. doi: 10.1039/c7cp03219f.

DOI:10.1039/c7cp03219f
PMID:28796266
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC5718296/
Abstract

Base-washed graphene-oxide which has been sequentially-modified by thiol-epoxy chemistry, results in materials with ice-nucleation activity. The role of hydro-philic/phobic grafts and polymers was evaluated with the most potent functioning at just 0.25 wt%. These 2-D hybrid materials may find use in cryopreservation and fundamental studies on ice formation.

摘要

经过硫醇-环氧化学顺序改性的碱洗氧化石墨烯会产生具有冰核活性的材料。亲水性/疏水性接枝物和聚合物的作用在仅0.25 wt%时就具有最强的功能。这些二维杂化材料可能会用于低温保存和冰形成的基础研究。

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本文引用的文献

1
One-step grafting of polymers to graphene oxide.聚合物与氧化石墨烯的一步接枝
Polym Chem. 2015 Dec 28;6(48):8270-8274. doi: 10.1039/C5PY01358E.
2
Graphene Oxide Restricts Growth and Recrystallization of Ice Crystals.氧化石墨烯限制冰晶的生长和重结晶。
Angew Chem Int Ed Engl. 2017 Jan 19;56(4):997-1001. doi: 10.1002/anie.201609230. Epub 2016 Dec 15.
3
Regioregular Alternating Polyampholytes Have Enhanced Biomimetic Ice Recrystallization Activity Compared to Random Copolymers and the Role of Side Chain versus Main Chain Hydrophobicity.与无规共聚物相比,区域规整交替聚两性电解质具有增强的仿生冰重结晶活性以及侧链与主链疏水性的作用。
Biomacromolecules. 2017 Jan 9;18(1):295-302. doi: 10.1021/acs.biomac.6b01691. Epub 2016 Dec 23.
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The Many Faces of Heterogeneous Ice Nucleation: Interplay Between Surface Morphology and Hydrophobicity.多相冰成核的多种形态:表面形貌和疏水性的相互作用。
J Am Chem Soc. 2015 Oct 28;137(42):13658-69. doi: 10.1021/jacs.5b08748. Epub 2015 Oct 15.
5
Ice Nucleation Properties of Oxidized Carbon Nanomaterials.氧化碳纳米材料的冰核形成特性
J Phys Chem Lett. 2015 Aug 6;6(15):3012-6. doi: 10.1021/acs.jpclett.5b01096. Epub 2015 Jul 20.
6
Probing the Biomimetic Ice Nucleation Inhibition Activity of Poly(vinyl alcohol) and Comparison to Synthetic and Biological Polymers.探究聚乙烯醇的仿生冰核抑制活性及其与合成聚合物和生物聚合物的比较
Biomacromolecules. 2015 Sep 14;16(9):2820-6. doi: 10.1021/acs.biomac.5b00774. Epub 2015 Aug 14.
7
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Covalently Binding Atomically Designed Au9 Clusters to Chemically Modified Graphene.将原子设计的Au9簇共价结合到化学修饰的石墨烯上。
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