钯（0）催化的烯烃碳杂官能化反应的最新进展
Recent Developments in Pd(0)-Catalyzed Alkene Carboheterofunctionalization Reactions.
作者信息
Garlets Zachary J, White Derick R, Wolfe John P
机构信息
Department of Chemistry, University of Michigan, 930 N. University Ave, Ann Arbor, MI, 48109-1055, USA.
出版信息
Asian J Org Chem. 2017 Jun;6(6):636-653. doi: 10.1002/ajoc.201600577. Epub 2017 Mar 10.
Abstract
This review summarizes recent developments in palladium-catalyzed alkene carboalkoxylation and carboamination reactions. New synthetic methods that have been reported in the past four years are described, along with mechanistic issues and the influence of mechanism on product stereochemistry. The applications of these transformations to the synthesis of natural products and other biologically relevant compounds are also discussed.
摘要
本综述总结了钯催化的烯烃碳烷氧基化和碳胺化反应的最新进展。描述了过去四年中报道的新合成方法，以及反应机理问题和机理对产物立体化学的影响。还讨论了这些转化反应在天然产物及其他具有生物活性的化合物合成中的应用。
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