Fornwald Ryan M, Fritz Jonathan A, Wolfe John P
Department of Chemistry, University of Michigan, 930 N. University Ave, Ann Arbor, MI 48109-1055 (USA).
Chemistry. 2014 Jul 7;20(28):8782-90. doi: 10.1002/chem.201402258. Epub 2014 Jun 17.
The Pd-catalyzed coupling of N-allylsulfamides with aryl and alkenyl triflates to afford cyclic sulfamide products is described. In contrast to other known Pd-catalyzed alkene carboamination reactions, these transformations may be selectively induced to occur by way of either anti- or syn-aminopalladation mechanistic pathways by modifying the catalyst structure and reaction conditions.
描述了钯催化的N-烯丙基磺酰胺与芳基和烯基三氟甲磺酸酯的偶联反应，以生成环状磺酰胺产物。与其他已知的钯催化的烯烃碳胺化反应不同，通过改变催化剂结构和反应条件，这些转化反应可以通过反式或顺式氨基钯化机理途径选择性地诱导发生。
