通过水相主体-客体络合作用实现形状可控和荧光超分子有机框架。
Shape-Controllable and Fluorescent Supramolecular Organic Frameworks Through Aqueous Host-Guest Complexation.
机构信息
Key Laboratory of Synthetic and Natural Functional Molecule Chemistry of the Ministry of Education, College of Chemistry and Materials Science, Northwest University, Xi'an, 710069, P. R. China.
Shanghai Synchrotron Radiation Facility, Shanghai Institute of Applied Physics, Chinese Academy of Sciences, Shanghai, 201204, China.
出版信息
Angew Chem Int Ed Engl. 2018 Jan 15;57(3):729-733. doi: 10.1002/anie.201710553. Epub 2017 Dec 14.
Two kinds of shape-controllable and fluorescent supramolecular organic frameworks (cuboid or spheroid) are constructed hierarchically from CB[8] and tetraphenylethylene derivatives through host-guest interaction in water. These two fluorescent SOFs exhibit intriguing and varied photophysical properties, including large red-shifts (up to 82 nm) and stimuli-responsive behavior to competitive guest by binding with CB[8], the turn-on fluorescence of which is applied in cellular imaging.
两种形状可控的荧光超分子有机框架（长方体或球体）通过主体-客体相互作用在水中从 CB[8]和四苯乙烯衍生物构筑而成。这两种荧光 SOF 表现出有趣且多样的光物理性质，包括大的红移（高达 82nm）和对与 CB[8]结合的竞争客体的刺激响应行为，其开启荧光可用于细胞成像。
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