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利用干涉全息术对单轴取向聚乙烯薄膜进行表面微图案化,用于应变传感器。

Surface Micropatterning of Uniaxially Oriented Polyethylene Films Using Interference Holography for Strain Sensors.

机构信息

Laboratory of Functional Organic Materials and Devices, Eindhoven University of Technology , P.O. Box 513, 5600 MB Eindhoven, The Netherlands.

DSM Materials Science Center , NL-6160 MD Geleen, The Netherlands.

出版信息

Langmuir. 2017 Dec 26;33(51):14592-14598. doi: 10.1021/acs.langmuir.7b03599. Epub 2017 Dec 14.

Abstract

A new procedure is presented for direct generation of surface micropatterns on uniaxially oriented polyethylene (PE) films using interference holography with a nanosecond pulsed laser. An ultraviolet absorber, 2-(2H-benzotriazol-2-yl)-4,6-di-tert-pentylphenol (BZT) is incorporated into PE prior to stretching to generate absorption at the wavelength of the laser. Illumination with an interference pattern in the absorption band of BZT leads to an obvious height variation in the exposed regions and consequently relief gratings are generated. The height in the exposed regions is strongly dependent on the angle between the grating direction and the film orientation direction. This phenomenon is attributed to a combination of events such as melting, entropic contraction, recrystallization, thermal evaporation of BZT, and anisotropic thermal conductivity. It is shown that the relief height increases with increasing BZT concentration and exhibits a linear dependence on the energy dose above a certain threshold. Additionally, the oriented PE films with the surface micropatterns are explored for strain sensors. The results demonstrate that small strains below 10% are monitored accurately in tensile deformation of the micropatterned, oriented PE films which makes these films potentially useful as strain sensors.

摘要

提出了一种新的方法,用于使用纳秒脉冲激光干涉全息术在单轴取向聚乙烯(PE)薄膜上直接生成表面微图案。将紫外线吸收剂 2-(2H-苯并三唑-2-基)-4,6-二叔戊基苯酚(BZT)掺入 PE 中,然后进行拉伸,以使激光波长处产生吸收。在 BZT 的吸收带中用干涉图案照射会导致暴露区域的明显高度变化,从而产生浮雕光栅。暴露区域的高度强烈依赖于光栅方向和薄膜取向方向之间的角度。这种现象归因于多种事件的组合,例如熔化、熵收缩、再结晶、BZT 的热蒸发和各向异性热导率。结果表明,浮雕高度随 BZT 浓度的增加而增加,并在超过一定阈值的能量剂量上表现出线性依赖性。此外,还探索了具有表面微图案的取向 PE 薄膜作为应变传感器。结果表明,在微图案化的取向 PE 薄膜的拉伸变形中,可以准确监测低于 10%的小应变,这使得这些薄膜有可能作为应变传感器使用。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/0e05/6150734/6f4da73d321f/la-2017-035996_0001.jpg

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