一种通过有机光氧化还原催化从芳基硼酸酯生成芳基自由基的策略：缺电子烯烃的光-迈尔外因型芳基化反应。
A strategy for generating aryl radicals from arylborates through organic photoredox catalysis: photo-Meerwein type arylation of electron-deficient alkenes.
作者信息
Iwata Y, Tanaka Y, Kubosaki S, Morita T, Yoshimi Y
机构信息
Department of Applied Chemistry and Biotechnology, Graduate School of Engineering, University of Fukui, 3-9-1 Bunkyo, Fukui 910-8507, Japan.
出版信息
Chem Commun (Camb). 2018 Jan 31;54(10):1257-1260. doi: 10.1039/c7cc09140k.
PMID:29340358
Abstract
Photoinduced reactions of arylboronic acids with electron deficient alkenes under mild organic photoredox catalysis conditions lead to the formation of Meerwein arylation type adducts via the generation of aryl radicals.
摘要
在温和的有机光氧化还原催化条件下，芳基硼酸与缺电子烯烃的光诱导反应通过芳基自由基的生成导致形成迈尔外因芳基化型加合物。
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