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单壁碳纳米管中的激子及其动力学

Excitons in Single-Walled Carbon Nanotubes and Their Dynamics.

作者信息

Amori Amanda R, Hou Zhentao, Krauss Todd D

机构信息

Department of Chemistry, University of Rochester, Rochester, New York 14627, USA; email:

The Institute of Optics, University of Rochester, Rochester, New York 14627, USA.

出版信息

Annu Rev Phys Chem. 2018 Apr 20;69:81-99. doi: 10.1146/annurev-physchem-050317-014241. Epub 2018 Jan 24.

Abstract

Understanding exciton dynamics in single-walled carbon nanotubes (SWCNTs) is essential to unlocking the many potential applications of these materials. This review summarizes recent progress in understanding exciton photophysics and, in particular, exciton dynamics in SWCNTs. We outline the basic physical and electronic properties of SWCNTs, as well as bright and dark transitions within the framework of a strongly bound one-dimensional excitonic model. We discuss the many facets of ultrafast carrier dynamics in SWCNTs, including both single-exciton states (bright and dark) and multiple-exciton states. Photophysical properties that directly relate to excitons and their dynamics, including exciton diffusion lengths, chemical and structural defects, environmental effects, and photoluminescence photon statistics as observed through photon antibunching measurements, are also discussed. Finally, we identify a few key areas for advancing further research in the field of SWCNT excitons and photonics.

摘要

了解单壁碳纳米管(SWCNT)中的激子动力学对于开发这些材料的众多潜在应用至关重要。本综述总结了在理解激子光物理,特别是单壁碳纳米管中激子动力学方面的最新进展。我们概述了单壁碳纳米管的基本物理和电子特性,以及在强束缚一维激子模型框架内的明亮和暗跃迁。我们讨论了单壁碳纳米管中超快载流子动力学的多个方面,包括单激子态(明亮和暗)和多激子态。还讨论了与激子及其动力学直接相关的光物理性质,包括激子扩散长度、化学和结构缺陷、环境效应以及通过光子反聚束测量观察到的光致发光光子统计。最后,我们确定了在单壁碳纳米管激子和光子学领域推进进一步研究的几个关键领域。

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