立体发散催化
Stereodivergent Catalysis.
作者信息
Beletskaya Irina P, Nájera Carmen, Yus Miguel
机构信息
Chemistry Department , M. V. Lomonosov Moscow State University , Leninskie Gory 1 , 119992 Moscow , Russia.
Departamento de Química Orgánica and Centro de Innovación en Química Avanzada (ORFEO-CINQA) , Universidad de Alicante , Apdo. 99 , E-03080 Alicante , Spain.
出版信息
Chem Rev. 2018 May 23;118(10):5080-5200. doi: 10.1021/acs.chemrev.7b00561. Epub 2018 Apr 20.
This review covers diastereo- and enantiodivergent catalyzed reactions in acyclic and cyclic systems using metal complexes or organocatalysts. Among them, nucleophilic addition to carbon-carbon and carbon-nitrogen double bonds, α-functionalization of carbonyl compounds, allylic substitutions, and ring opening of oxiranes and aziridines are considered. The diastereodivergent synthesis of alkenes from alkynes is also included. Finally, stereodivergent intramolecular and intermolecular cycloadditions and other cyclizations are also reported.
本综述涵盖了使用金属配合物或有机催化剂在无环和环状体系中进行的非对映和对映发散催化反应。其中包括对碳 - 碳和碳 - 氮双键的亲核加成、羰基化合物的α-官能化、烯丙基取代以及环氧乙烷和氮杂环丙烷的开环反应。还包括从炔烃非对映发散合成烯烃。最后，也报道了立体发散的分子内和分子间环加成反应以及其他环化反应。
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