Department of Safety, Health and Environmental Engineering, National Kaohsiung University of Science and Technology, Kaohsiun 824, Taiwan.
Institute of Labor, Occupational Safety and Health, Ministry of Labor, New Taipei City 221, Taiwan.
Int J Environ Res Public Health. 2018 May 3;15(5):899. doi: 10.3390/ijerph15050899.
Exposure to lead-containing dusts is a global public health concern. This work addresses an important issue of whether eco-friendly water-based paints reduce the exposure potential of auto-repainting workers to metals. With this aim, metal levels in automobile paints and worker metal exposure were measured using both solvent- and water-based paints. The levels of metals, and particularly Pb, Cr (total), Fe, and Cu, in solvent-based paints varied greatly among colors and brands. Lead concentrations ranged from below the detection limit (~0.25 μg/g) to 107,928 μg/g (dry film) across all samples. In water-based paints, the concentrations of Pb and Cr (total) were generally two to three orders of magnitude lower, but the concentrations of Al and Cu exceeded those in some solvent-based paints. The personal short-term exposure of workers who applied water-based paints of popular colors, such as black and white, were generally low, with Pb levels of less than <4 µg/m³ and Cr (total) levels of less than 1 µg/m³. Conversely, mean short-term exposure to Pb during the painting of a yellow cab using solvent-based paints were 2028 µg/m³, which was ~14 times the Taiwan short-term permissible exposure limit, while the mean level of exposure to Cr (total) was 290 µg/m³, which was well below the exposure limit. This study demonstrates that water-based paints reduce the exposure potential to lead, and highlights the importance of source control in limiting the toxic metals in paints.
接触含铅粉尘是一个全球性的公共卫生问题。本研究旨在探讨环保型水性涂料是否会降低汽车重新涂装工人接触金属的潜在风险,以解决这一重要问题。为此,采用溶剂型和水性涂料测量了汽车涂料中的金属水平和工人的金属暴露量。溶剂型涂料中各种颜色和品牌之间金属(尤其是 Pb、Cr(总)、Fe 和 Cu)的水平差异很大。所有样品中 Pb 的浓度范围从检测限以下(~0.25μg/g)到 107928μg/g(干膜)。在水性涂料中,Pb 和 Cr(总)的浓度通常低两个到三个数量级,但 Al 和 Cu 的浓度超过了一些溶剂型涂料。工人应用黑色和白色等流行颜色的水性涂料进行短期个人暴露时,浓度通常较低,Pb 浓度低于<4μg/m³,Cr(总)浓度低于 1μg/m³。相反,使用溶剂型涂料涂装黄色出租车时,工人短期暴露 Pb 的平均值为 2028μg/m³,是台湾短期允许暴露限值的 14 倍左右,而暴露于 Cr(总)的平均值为 290μg/m³,远低于暴露限值。本研究表明,水性涂料可降低铅的暴露风险,并强调了源控制在限制涂料中有毒金属方面的重要性。