College of Environmental Science and Engineering, Nankai University, Tianjin 300350, China.
National Engineering Research Center of Urban Environmental Pollution Control, Beijing Municipal Research Institute of Environment Protection, Beijing 100037, China.
Sci Total Environ. 2017 Dec 15;603-604:57-65. doi: 10.1016/j.scitotenv.2017.05.247. Epub 2017 Jun 14.
Epidemiologic studies regarding solvent-based paints (SBPs) containing VOCs have demonstrated a strong correlation between chronic and acute adverse health effects and the SBPs. Therefore, new environmentally friendly paints as substitutes containing less or none VOCs have been rapidly developed in research for future sustainable use. However, a few studies focusing on penetration and exposure condition of the substitute have been reported duo to the complexity and inaccessibility of painting industry. Surveys specifically looking at the present status of exposure condition were conducted to ascertain the popularization of water-based paints (WBPs) which concluded that markers of SBPs were detected in all 134 samples indicating bad industrial penetration. VOCs exposure concentrations of painters ranged from 3.8 to 18.2mg/m for WBPs, 3.5×10 to 14.8×10mg/m for SBPs, respectively. The negative correlation between ambient concentration and breathing zone concentration suggested the former was incapable of representing the actual exposure concentration. The real-time concentration was proved to be closely associated with the activity patterns while the mean concentration level was found mostly dependent on the paint types. Authentic inhalation dose ranged from 7.68 to 15.84mg (WBPs) and 3.84 to 15.59g (SBPs), respectively, for occupational painters (work 8h per day) and the total inhalation dose was estimated through a new conception. The findings suggested that WBPs could significantly reduce VOCs emission and occupational exposure.
关于含挥发性有机化合物(VOCs)的溶剂型涂料(SBPs)的流行病学研究表明,慢性和急性不良健康影响与 SBPs 之间存在很强的相关性。因此,作为替代品的新型环保涂料,含有较少或不含 VOCs 的涂料,已在未来可持续使用的研究中迅速发展。然而,由于涂料行业的复杂性和难以进入,很少有研究关注替代品的渗透和暴露条件。专门针对暴露条件现状进行的调查旨在确定水性涂料(WBPs)的普及程度,调查结果表明,在所有 134 个样本中都检测到了 SBPs 的标志物,这表明工业渗透情况不佳。画家的 VOCs 暴露浓度范围为 3.8 至 18.2mg/m3,用于 WBPs;3.5×10 至 14.8×10mg/m3,用于 SBPs。环境浓度与呼吸区浓度之间的负相关表明前者无法代表实际暴露浓度。实时浓度被证明与活动模式密切相关,而平均浓度水平主要取决于涂料类型。职业画家(每天工作 8 小时)的实际吸入剂量范围为 7.68 至 15.84mg(WBPs)和 3.84 至 15.59g(SBPs),通过新概念估算了总吸入剂量。研究结果表明,WBPs 可以显著减少 VOCs 的排放和职业暴露。