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木本种子油中中长链脂肪酸谱的化学表征及氧化稳定性

Chemical Characterization and Oxidative Stability of Medium- and Long-Chain Fatty Acid Profiles in Tree-Borne Seed Oils.

作者信息

Kim Da-Som, Kim Hoe-Sung, Lee Kyoung-Tae, Hong Dong-Lee, Cho Sung-Rae, Pan Jeong Hoon, Park Yong Bae, Lee Yang-Bong, Kim Jae Kyeom, Shin Eui-Cheol

机构信息

Department of Food Science, Gyeongnam National University of Science and Technology, Jinju 52725, Republic of Korea.

Southern Forest Resources Research Center, National Institute of Forest Science, Jinju 52817, Republic of Korea.

出版信息

J Anal Methods Chem. 2018 Apr 1;2018:2178684. doi: 10.1155/2018/2178684. eCollection 2018.

Abstract

This study was undertaken to evaluate chemical characteristics and oxidative stability of tree-borne seed oils. A total of 15 different fatty acids were identified in six tree-borne seed oils, which included seven types of saturated fatty acids, four types of monounsaturated fatty acids, and four types of polyunsaturated fatty acids. Japanese camphor tree (JCT) had a high content of medium-chain fatty acids (97.94 ± 0.04%), in which fatty acid composition was distinct from those of the other five plant seed oils. Overall, contents of tocopherols, a type of fat-soluble vitamin, ranged between 3.82 ± 0.04 mg/100 g and 101.98 ± 1.34 mg/100 g, respectively. Phytosterol contents ranged from 117.77 ± 1.32 mg/100 g to 479.45 ± 4.27 mg/100 g, respectively. Of all tree-borne seed oils, -sitosterol was the phytosterol at the highest concentration. Contents of unsaponifiables were between 0.13 ± 0.08 and 2.01 ± 0.02, and values of acid, peroxide, and -anisidine were between 0.79 ± 0.01 and 38.94 ± 0.24 mg KOH/g, 3.53 ± 0.21 and 127.67 ± 1.79 meq/kg, and 2.07 ± 0.51 and 9.67 ± 0.25, respectively. Oxidative stability of tree-borne seed oils was assessed through measurement of oxidation-induction periods. These results should serve as a foundation to identify the potential of tree-borne seed oils in industrial application as well as in providing fundamental data.

摘要

本研究旨在评估木本种子油的化学特性和氧化稳定性。在六种木本种子油中总共鉴定出15种不同的脂肪酸,其中包括七种饱和脂肪酸、四种单不饱和脂肪酸和四种多不饱和脂肪酸。日本樟树(JCT)的中链脂肪酸含量很高(97.94±0.04%),其脂肪酸组成与其他五种植物种子油不同。总体而言,生育酚(一种脂溶性维生素)的含量分别在3.82±0.04mg/100g至101.98±1.34mg/100g之间。植物甾醇含量分别在117.77±1.32mg/100g至479.45±4.27mg/100g之间。在所有木本种子油中,β-谷甾醇是浓度最高的植物甾醇。不皂化物含量在0.13±0.08至2.01±0.02之间,酸值、过氧化值和对茴香胺值分别在0.79±0.01至38.94±0.24mg KOH/g、3.53±0.21至127.67±1.79meq/kg和2.07±0.51至9.67±0.25之间。通过测量氧化诱导期来评估木本种子油的氧化稳定性。这些结果应作为确定木本种子油在工业应用中的潜力以及提供基础数据的基础。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/d420/5901951/82b839a16562/JAMC2018-2178684.001.jpg

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