Lozano Gabriel
Institute of Materials Science of Seville , Spanish National Research Council-University of Seville , Americo Vespucio 49 , 41092 , Seville , Spain.
J Phys Chem Lett. 2018 Jul 19;9(14):3987-3997. doi: 10.1021/acs.jpclett.8b01417. Epub 2018 Jul 6.
The development of smart illumination sources represents a central challenge for current technology. In this context, the quest for novel materials that enable efficient light generation is essential. Metal halide compounds with perovskite crystalline structure (ABX) have gained tremendous interest in the last five years since they come as easy-to-prepare high performance semiconductors. Perovskite absorbers are driving the power-conversion-efficiencies of thin film photovoltaics to unprecedented values. Nowadays, mixed-cation, mixed-halide lead perovskite solar cells reach efficiencies consistently over 20% and promise to get close to 30% in multijunction devices when combined with silicon cells at no surcharge. Nonetheless, perovskites' fame extends further since extensive research on these novel semiconductors has also revealed their brightest side. Soon after their irruption in the photovoltaic scenario, demonstration of efficient color tunable-with high color purity-perovskite emitters has opened new avenues for light generation applications that are timely to discuss herein.
智能照明光源的发展是当前技术面临的一项核心挑战。在这种背景下,寻找能够实现高效光生成的新型材料至关重要。具有钙钛矿晶体结构(ABX)的金属卤化物化合物在过去五年中引起了极大的关注,因为它们是易于制备的高性能半导体。钙钛矿吸收体正在将薄膜光伏的功率转换效率提升至前所未有的水平。如今,混合阳离子、混合卤化物铅钙钛矿太阳能电池的效率始终超过20%,并且在与硅电池组合形成多结器件时,有望在不增加成本的情况下接近30%。尽管如此,钙钛矿的声誉还不止于此,因为对这些新型半导体的广泛研究还揭示了它们最出色的一面。在它们闯入光伏领域后不久,高效的、具有高色纯度的颜色可调谐钙钛矿发光体的展示为光生成应用开辟了新途径,本文将适时对此进行讨论。