Durmaz Mustafa, Halay Erkan, Bozkurt Selahattin
Department of Chemistry Education, Ahmet Kelesoglu Education Faculty, Necmettin Erbakan University, 42090 Konya, Turkey.
Department of Chemistry and Chemical Processing Technologies, Banaz Vocational School, Usak University, Usak, Turkey.
Beilstein J Org Chem. 2018 Jun 8;14:1389-1412. doi: 10.3762/bjoc.14.117. eCollection 2018.
The use of calixarenes in asymmetric catalysis is receiving increasing attention due to their tunable three-dimensional molecular platforms along with their easy syntheses and versatile modification at the upper and lower rims. This review summarizes the recent progress of synthesis and use of chiral calixarenes in asymmetric syntheses which emerged later than 2010.
由于杯芳烃具有可调节的三维分子平台,且易于合成,其上下边缘还能进行多种修饰,因此它们在不对称催化中的应用正受到越来越多的关注。本综述总结了2010年以后出现的手性杯芳烃在不对称合成中的合成及应用方面的最新进展。