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高效实用的醇类经碘催化剂促进的有氧氧化制备醛酮。

Highly practical and efficient preparation of aldehydes and ketones from aerobic oxidation of alcohols with an inorganic-ligand supported iodine catalyst.

机构信息

School of Chemical and Environmental Engineering, Shanghai Institute of Technology, Shanghai 201418, P. R. China.

出版信息

Chem Commun (Camb). 2018 Sep 6;54(72):10164-10167. doi: 10.1039/c8cc03722a.

DOI:10.1039/c8cc03722a
PMID:30137065
Abstract

Herein, we divulge an efficient protocol for aerobic oxidation of alcohols with an inorganic-ligand supported iodine catalyst, (NH4)5[IMo6O24]. The catalyst system is compatible with a wide range of groups and exhibits high selectivity, and shows excellent stability and reusability, thus serving as a potentially greener alternative to the classical transformations.

摘要

在此,我们披露了一种使用无机配体支持的碘催化剂(NH4)5[IMo6O24]实现醇的有氧氧化的有效方法。该催化剂体系与多种官能团兼容,具有高选择性,并表现出优异的稳定性和可重复使用性,因此是经典转化的潜在绿色替代方案。

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