Marko IE, Giles PR, Tsukazaki M, Brown SM, Urch CJ
I. E. Marko, P. R. Giles, M. Tsukazaki, Universite Catholique de Louvain, Departement de Chimie, Laboratoire de Chimie Organique, Batiment Lavoisier, Place Louis Pasteur 1, B-1348 Louvain-la-Neuve, Belgium. S. M. Brown, Zeneca Process Technology Department Huddersfield Works, P.O.Box A38, Leeds Road, Huddersfield HD2 1FF, United Kingdom. C. J. Urch, Zeneca Agrochemicals, Jealott's Hill Research Station, Bracknell, Berkshire RG42 6ET, United Kingdom.
Science. 1996 Dec 20;274(5295):2044-6. doi: 10.1126/science.274.5295.2044.
An efficient, copper-based catalyst has been discovered that oxidizes a wide range of alcohols into aldehydes and ketones under mild conditions. This catalytic system utilizes oxygen or air as the ultimate, stoichiometric oxidant, producing water as the only by-product.
人们发现了一种高效的铜基催化剂,它能在温和条件下将多种醇氧化为醛和酮。该催化体系利用氧气或空气作为最终的化学计量氧化剂,仅产生水作为唯一的副产物。