Lam Jolie, Szkop Kevin M, Mosaferi Eliar, Stephan Douglas W
Department of Chemistry, University of Toronto, 80 St. George St., Toronto, Ontario M5S3H6, Canada.
Chem Soc Rev. 2019 Jul 1;48(13):3592-3612. doi: 10.1039/c8cs00277k.
This article is focused on recent developments in main group mediated hydrogenation chemistry and catalysis using "frustrated Lewis pairs" (FLPs). The broading range of substrates and catalyst systems is reviewed and the advances in catalytic reductions and the development of stereoselective, asymmetric reductions made since 2012 is considered.
本文聚焦于主族介导的氢化化学以及使用“受阻路易斯酸碱对”(FLPs)的催化反应的最新进展。综述了底物和催化剂体系的广泛范围,并探讨了自2012年以来催化还原方面的进展以及立体选择性、不对称还原反应的发展情况。