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引用本文的文献

1
Response to comment on 'Hydrogen bonds in crystalline d-alanine: diffraction and spectroscopic evidence for differences between enantiomers'.对《结晶d-丙氨酸中的氢键:对映体之间差异的衍射和光谱证据》评论的回应
IUCrJ. 2018 Jul 27;5(Pt 5):658-659. doi: 10.1107/S2052252518010321. eCollection 2018 Sep 1.

本文引用的文献

1
Hydrogen bonds in crystalline d-alanine: diffraction and spectroscopic evidence for differences between enantiomers.结晶态d-丙氨酸中的氢键:对映体之间差异的衍射和光谱证据
IUCrJ. 2018 Jan 1;5(Pt 1):6-12. doi: 10.1107/S2052252517015573.
2
Dynamics and thermodynamics of crystalline polymorphs. 3. γ-Glycine, analysis of variable-temperature atomic displacement parameters, and comparison of polymorph stabilities.晶体多晶型物的动力学与热力学。3. γ-甘氨酸、变温原子位移参数分析及多晶型稳定性比较
J Phys Chem A. 2014 Oct 30;118(43):9951-9. doi: 10.1021/jp506659c. Epub 2014 Oct 16.
3
D- or L-alanine: that is the question.D- 型或 L- 型丙氨酸:这就是问题所在。
Chemphyschem. 2000 Aug 4;1(1):60-2. doi: 10.1002/1439-7641(20000804)1:1<60::AID-CPHC60>3.0.CO;2-M.
4
Electroweak quantum chemistry of alanine: parity violation in gas and condensed phases.丙氨酸的电弱量子化学:气相和凝聚相中的宇称破坏。
Chemphyschem. 2000 Aug 4;1(1):57-60. doi: 10.1002/1439-7641(20000804)1:1<57::AID-CPHC57>3.0.CO;2-J.
5
Raman and neutron scattering study of partially deuterated L-alanine: evidence of a solid-solid phase transition.拉曼和中子散射研究部分氘代 L-丙氨酸:固态-固态相变的证据。
Chemphyschem. 2009 Dec 21;10(18):3337-43. doi: 10.1002/cphc.200900482.
6
High-resolution spectroscopic studies and theory of parity violation in chiral molecules.手性分子中宇称不守恒的高分辨率光谱研究及理论
Annu Rev Phys Chem. 2008;59:741-69. doi: 10.1146/annurev.physchem.58.032806.104511.
7
First experimental evidence for the preferential stabilization of the natural D- over the nonnatural L-configuration in nucleic acids.核酸中天然D-构型相对于非天然L-构型优先稳定的首个实验证据。
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8
First look at RNA in L-configuration.首先观察L构型的RNA。
Acta Crystallogr D Biol Crystallogr. 2004 Jan;60(Pt 1):1-7. doi: 10.1107/s0907444903027690. Epub 2003 Dec 18.
9
Anharmonicity in anisotropic displacement parameters.各向异性位移参数中的非谐性。
Acta Crystallogr A. 2000 Sep;56 (Pt 5):425-35. doi: 10.1107/s0108767300008734.
10
Precision neutron diffraction structure determination of protein and nucleic acid components. I. The crystal and molecular structure of the amino acid L-alanine.
J Am Chem Soc. 1972 Apr 19;94(8):2657-60. doi: 10.1021/ja00763a016.

对《结晶 D-丙氨酸中的氢键:对映体之间差异的衍射和光谱证据》的评论

Comments on 'Hydrogen bonds in crystalline d-alanine: diffraction and spectroscopic evidence for differences between enantiomers'.

作者信息

Bürgi Hans-Beat, Macchi Piero

机构信息

Department of Chemistry and Biochemistry, University of Bern, Freiestrasse 3, Bern, 3012, Switzerland.

Department of Chemistry, University of Zurich, Winterthurestrasse 190, Zurich, 8057, Switzerland.

出版信息

IUCrJ. 2018 Jul 27;5(Pt 5):654-657. doi: 10.1107/S2052252518007406. eCollection 2018 Sep 1.

DOI:10.1107/S2052252518007406
PMID:30224968
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6126655/
Abstract

The recent paper by Belo, Pereira, Freire, Argyriou, Eckert & Bordallo [(2018 ▸), , , 6-12] reports observations that may lead one to think of very strong and visible consequences of the parity-violation energy difference between enantiomers of a molecule, namely alanine. If proved, this claim would have an enormous impact for research in structural chemistry. However, alternative, more realistic, explanations of their experiments have not been ruled out by the authors. Moreover, the theoretical calculations carried out to support the hypothesis are unable to differentiate between enantiomers (molecules or crystals). Therefore, the conclusions drawn by Belo (2018 ▸) are deemed inappropriate as the data presented do not contain sufficient information to reach such a conclusion.

摘要

贝洛、佩雷拉、弗雷雷、阿吉里奥、埃克特和博尔达洛最近发表的论文[(2018▸),,,6 - 12]报告了一些观察结果,这些结果可能会让人想到分子对映体(即丙氨酸)之间宇称破缺能量差所产生的非常强烈且明显的后果。如果这一说法得到证实,将对结构化学研究产生巨大影响。然而,作者并未排除对他们实验的其他更现实的解释。此外,为支持该假设所进行的理论计算无法区分对映体(分子或晶体)。因此,贝洛(2018▸)得出的结论被认为是不合适的,因为所呈现的数据并不包含足以得出该结论的充分信息。