Faculty of Chemistry and Biochemistry, Industrial Chemistry-, Nanostructured Catalyst Materials, Ruhr University Bochum, Universitätsstraße 150, 44801, Bochum, Germany.
Chemistry. 2019 Feb 6;25(8):1866-1882. doi: 10.1002/chem.201803887. Epub 2019 Jan 8.
In recent years, the synthesis of mixed-metal and mixed-linker metal-organic frameworks with multiple metals and/or linker molecules combined in one framework has become a growing field of interest. These mixed-component or multivariate metal-organic framework materials provide the possibility to introduce multiple functionalities inside one framework. The interaction of guest molecules with different functionalities in the same material is a promising approach in the fields of gas storage, separation, catalysis and drug delivery. Furthermore, the combination of different components may lead to synergistic effects that cannot be achieved otherwise. These mixed-component approaches open up new pathways to an even larger range of possible customizations in the field of metal-organic frameworks.
近年来，将多种金属和/或连接体分子组合在一个框架内的混合金属和混合连接体金属-有机骨架的合成已成为一个日益增长的研究领域。这些混合成分或多变量金属-有机骨架材料为在一个框架内引入多种功能提供了可能性。在气体储存、分离、催化和药物输送等领域，客体分子与同一材料中不同功能之间的相互作用是一种很有前途的方法。此外，不同成分的结合可能会导致协同效应，这是其他方法无法实现的。这些混合成分的方法为金属-有机骨架领域的进一步定制提供了更多的可能性。
