Chemistry Department, Payame Noor University, Tehran, 19395-4697, Islamic Republic of Iran.
Faculty of Medicine, Ilam University of Medical Sciences, Ilam, 69391-77143, Islamic Republic of Iran.
Mikrochim Acta. 2018 Sep 26;185(10):479. doi: 10.1007/s00604-018-3009-x.
A highly selective electrochemical sensor was fabricated based on a modified carbon paste electrode with zinc ferrite nanoparticles (ZnFeO NPs). The nanocomposite has attractive properties such as high surface-to-volume ratio and good electrocatalytic activity towards the drugs acetaminophen (AC), epinephrine (EP), and melatonin (MT), best at working voltages of 0.35, 0.09 and 0.55 V (vs. Ag/AgCl), respectively. The linear ranges (and detection limits) are 6.5-135 (0.4) μmol L for AC, 5-100 (0.7) μmol L for EP, and 6.5-145 (3) μmol L for MT. Graphical abstract A novel electrochemical sensor based on a modified carbon paste electrode with zinc ferrite nanoparticles (ZnFeO) for the simultaneous detection of the acetaminophen, epinephrine and melatonin was fabricated.
基于修饰后的碳糊电极和氧化锌纳米粒子(ZnFeO NPs),制备了一种高选择性电化学传感器。该纳米复合材料具有高的比表面积和对药物醋氨酚(AC)、肾上腺素(EP)和褪黑素(MT)的良好电催化活性等吸引人的特性,在工作电压分别为 0.35、0.09 和 0.55 V(相对于 Ag/AgCl)时表现最佳。AC 的线性范围(和检测限)为 6.5-135(0.4)μmol L,EP 的线性范围(和检测限)为 5-100(0.7)μmol L,MT 的线性范围(和检测限)为 6.5-145(3)μmol L。