Li Man-Bo, Inge A Ken, Posevins Daniels, Gustafson Karl P J, Qiu Youai, Bäckvall Jan-E
Department of Organic Chemistry, Arrhenius Laboratory , Stockholm University , SE-106 91 Stockholm , Sweden.
Department of Materials and Environmental Chemistry, Arrhenius Laboratory , Stockholm University , SE-106 91 Stockholm , Sweden.
J Am Chem Soc. 2018 Nov 7;140(44):14604-14608. doi: 10.1021/jacs.8b09562. Epub 2018 Oct 29.
A palladium-catalyzed oxidative tandem process of enallenols was accomplished within a homogeneous/heterogeneous catalysis manifold, setting the stage for the highly chemodivergent and diastereoselective synthesis of γ-lactones and γ-lactams under mild conditions.
在均相/非均相催化体系中实现了钯催化的烯醇醛氧化串联反应，为在温和条件下高度化学发散和非对映选择性合成γ-内酯和γ-内酰胺奠定了基础。
