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文化遗产领域天然有机材料的中红外和近红外反射光谱数据库

Mid and Near-Infrared Reflection Spectral Database of Natural Organic Materials in the Cultural Heritage Field.

作者信息

Invernizzi Claudia, Rovetta Tommaso, Licchelli Maurizio, Malagodi Marco

机构信息

Arvedi Laboratory of Non-Invasive Diagnostics, CISRiC, University of Pavia, Via Bell'Aspa 3, 26100 Cremona, Italy.

Department of Mathematical, Physical and Computer Sciences, University of Parma, Parco Area delle Scienze, 7/A, 43124 Parma, Italy.

出版信息

Int J Anal Chem. 2018 Oct 1;2018:7823248. doi: 10.1155/2018/7823248. eCollection 2018.

DOI:10.1155/2018/7823248
PMID:30364094
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6188587/
Abstract

This study presents mid and near-infrared (7500-375 cm) total reflection mode spectra of several natural organic materials used in artworks as binding media, consolidants, adhesives, or protective coatings. A novel approach to describe and interpret reflectance bands as well as calculated absorbance after Kramers-Kronig transformation (KKT) is proposed. Transflection mode spectra have represented a valuable support both to study the distorted reflectance bands and to validate the applicability and usefulness of the KK correction. The aim of this paper is to make available to scientists and conservators a comprehensive infrared reflection spectral database, together with its detailed interpretation, as a tool for the noninvasive identification of proteins, lipids, polysaccharides, and resins by means of portable noncontact FTIR spectrometers.

摘要

本研究展示了几种用于艺术品的天然有机材料的中红外和近红外(7500 - 375厘米)全反射模式光谱,这些材料用作粘结介质、加固剂、粘合剂或保护涂层。提出了一种描述和解释反射带以及克喇末 - 克朗尼格变换(KKT)后计算吸光度的新方法。透反射模式光谱对于研究扭曲的反射带以及验证KK校正的适用性和有用性都提供了有价值的支持。本文的目的是为科学家和文物保护者提供一个全面的红外反射光谱数据库及其详细解释,作为通过便携式非接触傅里叶变换红外光谱仪对蛋白质、脂质、多糖和树脂进行非侵入式鉴定的工具。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/da50524b0c58/IJAC2018-7823248.009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/16f6e454eb58/IJAC2018-7823248.001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/2808f969a5b1/IJAC2018-7823248.002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/7c8a7ebcc4f4/IJAC2018-7823248.003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/c69cac230d39/IJAC2018-7823248.004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/0f853579838b/IJAC2018-7823248.005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/7fef5a1dfc36/IJAC2018-7823248.006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/99b1d8532fa0/IJAC2018-7823248.007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/1e1b4d41f487/IJAC2018-7823248.008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/da50524b0c58/IJAC2018-7823248.009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/16f6e454eb58/IJAC2018-7823248.001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/2808f969a5b1/IJAC2018-7823248.002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/7c8a7ebcc4f4/IJAC2018-7823248.003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/c69cac230d39/IJAC2018-7823248.004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/0f853579838b/IJAC2018-7823248.005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/7fef5a1dfc36/IJAC2018-7823248.006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/99b1d8532fa0/IJAC2018-7823248.007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/1e1b4d41f487/IJAC2018-7823248.008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/ea51/6188587/da50524b0c58/IJAC2018-7823248.009.jpg

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