Hydrogenation of CO to Formate with H : Transition Metal Free Catalyst Based on a Lewis Pair.

Hydrogenation of CO to formate with H in the absence of transition metal is a long-standing challenge in catalysis. The reactions between tris(pentafluorophenyl)borane (BCF) and K CO (or KHCO ) are found to form a Lewis pair (K [(BCF) -CO ]) which can react with both H and CO to produce formate. Based on these stoichiometric reactions, the first catalytic hydrogenation process of CO to formate using transition metal free catalyst (BCF/M CO , M=Na, K, and Cs) is reported. The highest TON value of this catalytic process is up to 3941. Further research revealed the reaction mechanism in which the Lewis pair enables the splitting of H and the insertion of CO into the B-H bond.