Vidal Fernando, Jäkle Frieder
Department of Chemistry, Rutgers University-Newark, 73 Warren Street, Newark, NJ, 07102, USA.
Angew Chem Int Ed Engl. 2019 Apr 23;58(18):5846-5870. doi: 10.1002/anie.201810611. Epub 2019 Feb 20.
The past decade has witnessed tremendous advances in the synthesis of polymers that contain elements from the main groups beyond those found in typical organic polymers. Unique properties that arise from dramatic differences in bonding and molecular geometry, electronic structure, and chemical reactivity, are exploited in diverse application fields. Herein we highlight recent advances in inorganic backbone polymers, discuss how Lewis acid/base functionalization of polymers results in unprecedented reactivity, and survey conjugated hybrids with unique electronic structures for sensor and device applications.
在过去十年中，聚合物合成领域取得了巨大进展，这些聚合物包含典型有机聚合物中不存在的主族元素。由键合、分子几何结构、电子结构和化学反应性的显著差异所产生的独特性能，在各种应用领域中得到了利用。本文中，我们重点介绍无机主链聚合物的最新进展，讨论聚合物的路易斯酸/碱官能化如何导致前所未有的反应活性，并概述具有独特电子结构的共轭杂化物在传感器和器件应用方面的情况。
