Titania-Based Hybrid Materials with ZnO, ZrO₂ and MoS₂: A Review.

Titania has properties that enable it to be used in a variety of applications, including self-cleaning surfaces, air and water purification systems, hydrogen evolution, and photoelectrochemical conversion. In order to improve the properties of titanium dioxide, modifications are made to obtain oxide/hybrid systems that are intended to have the properties of both components. In particular, zinc oxide, zirconia and molybdenum disulfide have been proposed as the second component of binary systems due to their antibacterial, electrochemical and photocatalytic properties. This paper presents a review of the current state of knowledge on the synthesis and practical utility of TiO₂-ZnO and TiO₂-ZrO₂ oxide systems and TiO₂-MoS₂ hybrid materials. The first part focuses on the hydrothermal method; then a review is made of the literature on the synthesis of the aforementioned materials using the sol-gel method. In the last section, the literature on the electrospinning method of synthesis is reviewed. The most significant physico-chemical, structural and dispersive-morphological properties of binary hybrid systems based on TiO₂ are described. A key aim of this review is to indicate the properties of TiO₂-ZnO, TiO₂-ZrO₂ and TiO₂-MoS₂ hybrid systems that have the greatest importance for practical applications. The variety of utilities of titania-based hybrid materials is emphasized.