铈光催化促进 1,2-二醇裂解为羰基化合物的可见光反应。
Visible-light mediated C-C bond cleavage of 1,2-diols to carbonyls by cerium-photocatalysis.
机构信息
Institute of Organic Chemistry, University of Regensburg, Universitätsstraße 31, 93053 Regensburg, Germany.
出版信息
Chem Commun (Camb). 2019 Jan 3;55(4):486-488. doi: 10.1039/c8cc09208g.
PMID:30548043
Abstract
We describe a photocatalytic method for the cleavage of vicinal diols to aldehydes and ketones. The reaction is catalyzed by blue light and a cerium-catalyst and the scope includes aryl as well as alkyl substituted diols. The simple protocol which works under air and at room temperature enables the valorization of abundant diols.
摘要
我们描述了一种光催化方法，用于裂解邻二醇为醛和酮。该反应由蓝光和铈催化剂催化，反应范围包括芳基和烷基取代的二醇。该简单的方案在空气和室温下进行，能够实现丰富的二醇的增值利用。
Zotero 插件