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基于冠醚的旋光性荧光传感器分子:一篇综述。

Optically active crown ether-based fluorescent sensor molecules: A mini-review.

作者信息

Móczár Ildikó, Huszthy Péter

机构信息

Department of Organic Chemistry and Technology, Budapest University of Technology and Economics, Budapest, Hungary.

出版信息

Chirality. 2019 Feb;31(2):97-109. doi: 10.1002/chir.23031. Epub 2018 Dec 28.

Abstract

This mini-review focuses on fluorescent optically active crown ethers (polymeric derivatives are not included) reported in the literature (according to our knowledge), of which enantiomeric recognition ability, and in some cases, also inorganic cation complexation properties, were investigated by the sensitive and versatile fluorescence spectroscopy. These crown ether-based chemosensors contain various fluorophore signaling units such as binaphthyl, anthracene, pyrene, tryptophan, benzimidazole, terpyridine, acridine, phenazine, acridone, BODIPY, and another conjugated aromatic one.

摘要

本综述聚焦于(据我们所知)文献中报道的荧光光学活性冠醚(不包括聚合物衍生物),其中对映体识别能力以及在某些情况下的无机阳离子络合特性,通过灵敏且通用的荧光光谱法进行了研究。这些基于冠醚的化学传感器包含各种荧光团信号单元,如联萘基、蒽、芘、色氨酸、苯并咪唑、三联吡啶、吖啶、吩嗪、吖啶酮、BODIPY以及另一种共轭芳香基团。

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