• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利：CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法，用中文像聊天一样搜索，搜遍4000万医学文献。AI智能推荐，让科研检索更轻松。

立即免费搜索

文件翻译

保留排版，准确专业，支持PDF/Word/PPT等文件格式，支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述，25分钟生成高质量综述，智能提取关键信息，辅助科研写作。

立即免费体验

聚氯乙烯含三聚氰胺席夫碱的形态和性能对紫外线的影响。

The Morphology and Performance of Poly(Vinyl Chloride) Containing Melamine Schiff Bases against Ultraviolet Light.

机构信息

Department of Optometry, College of Applied Medical Sciences, King Saud University, P.O. Box 10219, Riyadh 11433, Saudi Arabia.

National Center for Petrochemicals Technology, King Abdulaziz City for Science and Technology, P.O. Box 6086, Riyadh 11442, Saudi Arabia.

出版信息

Molecules. 2019 Feb 22;24(4):803. doi: 10.3390/molecules24040803.

DOI:10.3390/molecules24040803
PMID:30813367
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6413115/
Abstract

Five Schiff bases derived from melamine have been used as efficient additives to reduce the process of photodegradation of poly(vinyl chloride) films. The performance of Schiff bases has been investigated using various techniques. Poly(vinyl chloride) films containing Schiff bases were irradiated with ultraviolet light and any changes in their infrared spectra, weight, and the viscosity of their average molecular weight were investigated. In addition, the surface morphology of the films was inspected using a light microscope, atomic force microscopy, and a scanning electron micrograph. The additives enhanced the films resistance against irradiation and the polymeric surface was much smoother in the presence of the Schiff bases compared with the blank film. Schiff bases containing an ortho-hydroxyl group on the aryl rings showed the greatest photostabilization effect, which may possibly have been due to the direct absorption of ultraviolet light. This phenomenon seems to involve the transfer of a proton as well as several intersystem crossing processes.

摘要

五种由三聚氰胺衍生的席夫碱已被用作高效添加剂，以减少聚氯乙烯薄膜的光降解过程。使用各种技术研究了席夫碱的性能。含有席夫碱的聚氯乙烯薄膜用紫外线照射，并研究了它们的红外光谱、重量和平均分子量的粘度的任何变化。此外，还使用光学显微镜、原子力显微镜和扫描电子显微镜检查了薄膜的表面形貌。添加剂增强了薄膜对辐射的抵抗力，并且与空白薄膜相比，在存在席夫碱的情况下，聚合物表面更加光滑。在芳环上带有邻位羟基的席夫碱表现出最大的光稳定化效果，这可能是由于直接吸收了紫外线。这种现象似乎涉及质子转移和几个体系间交叉过程。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/3235db5330e6/molecules-24-00803-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/964b45fa668c/molecules-24-00803-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/1484a5159323/molecules-24-00803-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/8caf5e06f81c/molecules-24-00803-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/485997ee8a87/molecules-24-00803-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/7adcff79c76f/molecules-24-00803-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/e6aafb0b952d/molecules-24-00803-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/45dadae8f232/molecules-24-00803-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/da424a6ff143/molecules-24-00803-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/4fbdea6a98de/molecules-24-00803-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/67b9c3be0b65/molecules-24-00803-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/b2f74e798be8/molecules-24-00803-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/3235db5330e6/molecules-24-00803-g012.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/964b45fa668c/molecules-24-00803-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/1484a5159323/molecules-24-00803-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/8caf5e06f81c/molecules-24-00803-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/485997ee8a87/molecules-24-00803-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/7adcff79c76f/molecules-24-00803-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/e6aafb0b952d/molecules-24-00803-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/45dadae8f232/molecules-24-00803-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/da424a6ff143/molecules-24-00803-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/4fbdea6a98de/molecules-24-00803-g009.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/67b9c3be0b65/molecules-24-00803-g010.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/b2f74e798be8/molecules-24-00803-g011.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/de4c/6413115/3235db5330e6/molecules-24-00803-g012.jpg

相似文献

1
The Morphology and Performance of Poly(Vinyl Chloride) Containing Melamine Schiff Bases against Ultraviolet Light.聚氯乙烯含三聚氰胺席夫碱的形态和性能对紫外线的影响。
Molecules. 2019 Feb 22;24(4):803. doi: 10.3390/molecules24040803.
2
Poly(vinyl Chloride) Photostabilization in the Presence of Schiff Bases Containing a Thiadiazole Moiety.含噻二唑部分席夫碱的聚氯乙烯光稳定化。
Molecules. 2018 Apr 15;23(4):913. doi: 10.3390/molecules23040913.
3
New Tetra-Schiff Bases as Efficient Photostabilizers for Poly(vinyl chloride).新型四席夫碱作为聚氯乙烯的高效光稳定剂。
Molecules. 2017 Sep 9;22(9):1506. doi: 10.3390/molecules22091506.
4
The Effect of Ultraviolet Irradiation on the Physicochemical Properties of Poly(vinyl Chloride) Films Containing Organotin(IV) Complexes as Photostabilizers.含有机锡(IV)配合物的聚氯乙烯薄膜的紫外光辐射对其物理化学性质的影响。
Molecules. 2018 Jan 28;23(2):254. doi: 10.3390/molecules23020254.
5
Polyphosphates as Inhibitors for Poly(vinyl Chloride) Photodegradation.多聚磷酸盐作为聚氯乙烯光降解抑制剂。
Molecules. 2017 Oct 28;22(11):1849. doi: 10.3390/molecules22111849.
6
Photostabilization of Poly(vinyl chloride) by Organotin(IV) Compounds against Photodegradation.有机锡(IV)化合物对聚氯乙烯的光稳定化作用及其光降解。
Molecules. 2019 Oct 1;24(19):3557. doi: 10.3390/molecules24193557.
7
Long-Term Effect of Ultraviolet Irradiation on Poly(vinyl chloride) Films Containing Naproxen Diorganotin(IV) Complexes.含萘普生二有机锡（IV）配合物的聚（氯乙烯）薄膜的长期紫外线辐射效应。
Molecules. 2019 Jun 28;24(13):2396. doi: 10.3390/molecules24132396.
8
Photostabilizing Efficiency of PVC in the Presence of Schiff Bases as Photostabilizers.席夫碱作为光稳定剂存在时聚氯乙烯的光稳定效率
Molecules. 2015 Nov 4;20(11):19886-99. doi: 10.3390/molecules201119665.
9
Photostability and Performance of Polystyrene Films Containing 1,2,4-Triazole-3-thiol Ring System Schiff Bases.含1,2,4-三唑-3-硫醇环系席夫碱的聚苯乙烯薄膜的光稳定性及性能
Molecules. 2016 Dec 9;21(12):1699. doi: 10.3390/molecules21121699.
10
Influence of Polyphosphates on the Physicochemical Properties of Poly (Vinyl Chloride) after Irradiation with Ultraviolet Light.聚磷酸盐对聚氯乙烯经紫外线辐照后物理化学性质的影响
Polymers (Basel). 2020 Jan 10;12(1):193. doi: 10.3390/polym12010193.

引用本文的文献

1
Low-cost photocatalytic membrane modified with green heterojunction TiO/ZnO nanoparticles prepared from waste.由废弃物制备的绿色异质结TiO/ZnO纳米颗粒改性的低成本光催化膜
Sci Rep. 2023 Dec 13;13(1):22150. doi: 10.1038/s41598-023-49516-0.
2
Antimicrobially Active Zn(II) Complexes of Reduced Schiff Bases Derived from Cyclohexane-1,2-diamine and Fluorinated Benzaldehydes-Synthesis, Crystal Structure and Bioactivity.由环己烷-1,2-二胺和氟化苯甲醛衍生的还原席夫碱的具有抗菌活性的锌（II）配合物——合成、晶体结构及生物活性
Life (Basel). 2023 Jul 6;13(7):1516. doi: 10.3390/life13071516.
3
Preparation and Curing Mechanism of Modified Corn Straw by 3-Glycidyl Ether Oxypropyl Trimethoxysilane/Epoxy Resin Composites.

本文引用的文献

1
Incorporating fluorescent dyes into monodisperse melamine-formaldehyde resin microspheres via an organic sol-gel process: a pre-polymer doping strategy.通过有机溶胶-凝胶法将荧光染料掺入单分散三聚氰胺-甲醛树脂微球：一种预聚物掺杂策略。
J Mater Chem B. 2014 Sep 21;2(35):5837-5846. doi: 10.1039/c4tb00942h. Epub 2014 Jul 30.
2
Spectroscopic, Physical and Topography of Photochemical Process of PVC Films in the Presence of Schiff Base Metal Complexes.席夫碱金属配合物存在下PVC薄膜光化学过程的光谱、物理及形貌研究
Polymers (Basel). 2016 May 25;8(6):204. doi: 10.3390/polym8060204.
3
New Eco-Friendly Phosphorus Organic Polymers as Gas Storage Media.
3-缩水甘油醚氧丙基三甲氧基硅烷/环氧树脂复合材料改性玉米秸秆的制备及固化机理
Polymers (Basel). 2022 Dec 1;14(23):5233. doi: 10.3390/polym14235233.
4
Modifications of Polymers through the Addition of Ultraviolet Absorbers to Reduce the Aging Effect of Accelerated and Natural Irradiation.通过添加紫外线吸收剂对聚合物进行改性以降低加速辐照和自然辐照的老化效应。
Polymers (Basel). 2021 Dec 22;14(1):20. doi: 10.3390/polym14010020.
5
Substituted Organotin Complexes of 4-Methoxybenzoic Acid for Reduction of Poly(vinyl Chloride) Photodegradation.用于减少聚氯乙烯光降解的4-甲氧基苯甲酸取代有机锡配合物
Polymers (Basel). 2021 Nov 15;13(22):3946. doi: 10.3390/polym13223946.
6
Effect of Ultraviolet Irradiation on Polystyrene Containing Cephalexin Schiff Bases.紫外线照射对含头孢氨苄席夫碱的聚苯乙烯的影响。
Polymers (Basel). 2021 Sep 2;13(17):2982. doi: 10.3390/polym13172982.
7
Tin Complexes of 4-(Benzylideneamino)benzenesulfonamide: Synthesis, Structure Elucidation and Their Efficiency as PVC Photostabilizers.4-（亚苄基氨基）苯磺酰胺的锡配合物：合成、结构解析及其作为聚氯乙烯光稳定剂的效能
Polymers (Basel). 2021 Jul 23;13(15):2434. doi: 10.3390/polym13152434.
8
Tin-Naphthalene Sulfonic Acid Complexes as Photostabilizers for Poly(vinyl chloride).锡-萘磺酸复合物作为聚氯乙烯的光稳定剂。
Molecules. 2021 Jun 14;26(12):3629. doi: 10.3390/molecules26123629.
9
Synthesis of Carvedilol-Organotin Complexes and Their Effects on Reducing Photodegradation of Poly(Vinyl Chloride).卡维地洛有机锡配合物的合成及其对聚氯乙烯光降解的抑制作用
Polymers (Basel). 2021 Feb 6;13(4):500. doi: 10.3390/polym13040500.
10
Tin Complexes Containing an Atenolol Moiety as Photostabilizers for Poly(Vinyl Chloride).含阿替洛尔部分的锡配合物作为聚氯乙烯的光稳定剂
Polymers (Basel). 2020 Dec 6;12(12):2923. doi: 10.3390/polym12122923.
新型环保型磷有机聚合物作为气体储存介质
Polymers (Basel). 2017 Aug 3;9(8):336. doi: 10.3390/polym9080336.
4
Fabrication of Novel Ball-Like Polystyrene Films Containing Schiff Base Microspheres as Photostabilizers.含席夫碱微球作为光稳定剂的新型球状聚苯乙烯薄膜的制备
Polymers (Basel). 2018 Oct 24;10(11):1185. doi: 10.3390/polym10111185.
5
SEM analysis of the tunable honeycomb structure of irradiated poly(vinyl chloride) films doped with polyphosphate.掺有聚磷酸盐的辐照聚氯乙烯薄膜可调蜂窝结构的扫描电子显微镜分析
Heliyon. 2018 Dec 8;4(12):e01013. doi: 10.1016/j.heliyon.2018.e01013. eCollection 2018 Dec.
6
Fabrication of ordered honeycomb porous poly(vinyl chloride) thin film doped with a Schiff base and nickel(II) chloride.掺杂席夫碱和氯化镍（II）的有序蜂窝状多孔聚氯乙烯薄膜的制备
Heliyon. 2018 Aug 18;4(8):e00743. doi: 10.1016/j.heliyon.2018.e00743. eCollection 2018 Aug.
7
Poly(vinyl Chloride) Photostabilization in the Presence of Schiff Bases Containing a Thiadiazole Moiety.含噻二唑部分席夫碱的聚氯乙烯光稳定化。
Molecules. 2018 Apr 15;23(4):913. doi: 10.3390/molecules23040913.
8
The Effect of Ultraviolet Irradiation on the Physicochemical Properties of Poly(vinyl Chloride) Films Containing Organotin(IV) Complexes as Photostabilizers.含有机锡(IV)配合物的聚氯乙烯薄膜的紫外光辐射对其物理化学性质的影响。
Molecules. 2018 Jan 28;23(2):254. doi: 10.3390/molecules23020254.
9
New Tetra-Schiff Bases as Efficient Photostabilizers for Poly(vinyl chloride).新型四席夫碱作为聚氯乙烯的高效光稳定剂。
Molecules. 2017 Sep 9;22(9):1506. doi: 10.3390/molecules22091506.
10
SEM/EDS and optical microscopy analyses of microplastics in ocean trawl and fish guts.海洋拖网和鱼类肠道中微塑料的 SEM/EDS 和光学显微镜分析。
Sci Total Environ. 2017 Dec 15;603-604:616-626. doi: 10.1016/j.scitotenv.2017.06.047. Epub 2017 Jun 22.