Antoniac Iulian, Popescu Diana, Zapciu Aurelian, Antoniac Aurora, Miculescu Florin, Moldovan Horatiu
Physical Metallurgy, Department of Metallic Materials Science, University Politehnica of Bucharest, 060042 Bucharest, Romania.
Department of Machine and Manufacturing Systems, University Politehnica of Bucharest, 060042 Bucharest, Romania.
Materials (Basel). 2019 Mar 1;12(5):719. doi: 10.3390/ma12050719.
The main objective of this research is to prove the viability of obtaining magnesium (Mg) filled polylactic acid (PLA) biocomposites as filament feedstock for material extrusion-based additive manufacturing (AM). These materials can be used for medical applications, thus benefiting of all the advantages offered by AM technology in terms of design freedom and product customization. Filaments were produced from two PLA + magnesium + vitamin E (α-tocopherol) compositions and then used for manufacturing test samples and ACL (anterior cruciate ligament) screws on a low-cost 3D printer. Filaments and implant screws were characterized using SEM (scanning electron microscopy), FTIR (fourier transform infrared spectrometry), and DSC (differential scanning calorimetry) analysis. Although the filament manufacturing process could not ensure a uniform distribution of Mg particles within the PLA matrix, a good integration was noticed, probably due to the use of vitamin E as a precursor. The results also show that the composite biomaterials can ensure and maintain implant screws structural integrity during the additive manufacturing process.
本研究的主要目的是证明获得填充镁(Mg)的聚乳酸(PLA)生物复合材料作为基于材料挤出的增材制造(AM)的长丝原料的可行性。这些材料可用于医疗应用,从而受益于AM技术在设计自由度和产品定制方面提供的所有优势。长丝由两种PLA +镁+维生素E(α-生育酚)组合物制成,然后用于在低成本3D打印机上制造测试样品和前交叉韧带(ACL)螺钉。使用扫描电子显微镜(SEM)、傅里叶变换红外光谱(FTIR)和差示扫描量热法(DSC)分析对长丝和植入螺钉进行表征。尽管长丝制造过程不能确保Mg颗粒在PLA基质中均匀分布,但注意到有良好的结合,这可能是由于使用维生素E作为前体。结果还表明,复合生物材料可以在增材制造过程中确保并维持植入螺钉的结构完整性。