Wieme Tom, Duan Lingyan, Mys Nicolas, Cardon Ludwig, D'hooge Dagmar R
Centre for Polymer and Material Technologies, Department of Materials, Textiles and Chemical Engineering, Ghent University, Technologiepark 915, B-9052 Zwijnaarde (Ghent), Belgium.
Laboratory for Chemical Technology, Department of Materials, Textiles and Chemical Engineering, Ghent University, Technologiepark 914, B-9052 Zwijnaarde (Ghent), Belgium.
Polymers (Basel). 2019 Jan 8;11(1):87. doi: 10.3390/polym11010087.
To understand how the thermal conductivity (TC) of virgin commercial polymers and their composites with low graphite filler amounts can be improved, the effect of material choice, annealing and moisture content is investigated, all with feasible industrial applicability in mind focusing on injection molding. Comparison of commercial HDPE, PP, PLA, ABS, PS, and PA6 based composites under conditions minimizing the effect of the skin-core layer (measurement at half the sample thickness) allows to deduce that at 20 m% of filler, both the (overall) in- and through-plane TC can be significantly improved. The most promising results are for HDPE and PA6 (through/in-plane TC near 0.7/4.3 W·mK for HDPE and 0.47/4.3 W·mK for PA6 or an increase of 50/825% and 45/1200% respectively, compared to the virgin polymer). Testing with annealed and nucleated PA6 and PLA samples shows that further increasing the crystallinity has a limited effect. A variation of the average molar mass and moisture content is also almost without impact. Intriguingly, the variation of the measuring depth allows to control the relative importance of the TC of the core and skin layer. An increased measurement depth, hence, a higher core-to-skin ratio measurement specifically indicates a clear increase in the through-plane TC (e.g., factor 2). Therefore, for basic shapes, the removal of the skin layer is recommendable to increase the TC.
为了了解原始商用聚合物及其含少量石墨填料的复合材料的热导率(TC)如何得到改善,我们研究了材料选择、退火和含水量的影响,所有这些都是在考虑到注塑成型的可行工业适用性的情况下进行的。在尽量减少皮层-芯层效应的条件下(在样品厚度的一半处进行测量),对商用高密度聚乙烯(HDPE)、聚丙烯(PP)、聚乳酸(PLA)、丙烯腈-丁二烯-苯乙烯共聚物(ABS)、聚苯乙烯(PS)和聚酰胺6(PA6)基复合材料进行比较,可以推断出,当填料含量为20 m%时,(整体)面内和面外热导率都能得到显著提高。最有前景的结果是HDPE和PA6(HDPE的面外/面内热导率接近0.7/4.3 W·mK,PA6为0.47/4.3 W·mK,与原始聚合物相比,分别提高了50/825%和45/1200%)。对退火和成核的PA6和PLA样品进行测试表明,进一步提高结晶度的效果有限。平均摩尔质量和含水量的变化也几乎没有影响。有趣的是,测量深度的变化可以控制芯层和皮层热导率的相对重要性。因此,测量深度增加,即芯层与皮层的比例测量值更高,特别表明面外热导率有明显增加(例如,增加了2倍)。所以,对于基本形状的材料,建议去除皮层以提高热导率。
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