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用于光伏应用的自组装有机材料。

Self-Assembled Organic Materials for Photovoltaic Application.

作者信息

Ghosh Tanwistha, Panicker Jayanthy S, Nair Vijayakumar C

机构信息

Photosciences and Photonics Section, Council of Scientific and Industrial Research-National Institute for Interdisciplinary Science and Technology (CSIR-NIIST), Trivandrum 695019, India.

Academy of Scientific and Innovative Research (AcSIR), New Delhi 110001, India.

出版信息

Polymers (Basel). 2017 Mar 21;9(3):112. doi: 10.3390/polym9030112.

DOI:10.3390/polym9030112
PMID:30970792
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6431919/
Abstract

Organic photovoltaic cells based on bulk-heterojunction architecture have been a topic of intense research for the past two decades. Recent reports on power conversion efficiency surpassing 10% suggest these devices are a viable low-cost choice for a range of applications where conventional silicon solar cells are not suitable. Further improvements in efficiency could be achieved with the enhanced interaction between the donor and acceptor components. Effective utilization of supramolecular interactions to tailor and manipulate the communication between the components in the blend is a good strategy towards this end. Literature reports suggest that the long-term stability of organic solar cells, a major hurdle for commercial applications, can also be partially addressed by generating stable supramolecular nanostructures. In this review, we have made an attempt to summarize advances in small molecule, oligomer and polymer based systems, wherein supramolecular interactions such as hydrogen-bonding, pi-pi stacking, and dipole-dipole are explored for realizing stable and efficient bulk-heterojunction solar cells.

摘要

在过去二十年中，基于体异质结结构的有机光伏电池一直是深入研究的主题。最近有关功率转换效率超过10%的报告表明，对于一系列传统硅太阳能电池不适用的应用而言，这些器件是一种可行的低成本选择。通过增强供体和受体组件之间的相互作用，可以进一步提高效率。有效利用超分子相互作用来定制和操纵共混物中各组件之间的相互作用是实现这一目标的良好策略。文献报道表明，有机太阳能电池的长期稳定性作为商业应用的一个主要障碍，也可以通过生成稳定的超分子纳米结构来部分解决。在本综述中，我们试图总结基于小分子、低聚物和聚合物的系统的进展，其中探索了诸如氢键、π-π堆积和偶极-偶极等超分子相互作用，以实现稳定且高效的体异质结太阳能电池。

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