Suppr超能文献

用于防紫外线的聚甲基丙烯酸甲酯/醋酸丁酸纤维素透明共混物

Transparent Blend of Poly(Methylmethacrylate)/Cellulose Acetate Butyrate for the Protection from Ultraviolet.

作者信息

Mahmood Raouf Raouf, Abdul Wahab Zaidan, Azowa Ibrahim Nor, Abidin Talib Zainal, Chieng Buong Woei

机构信息

Department Of Physics, Faculty of Science, Universiti Putra Malaysia, 43400 UPM Serdang, Selangor, Malaysia.

Materials Engineering Department, College Of Engineering, Al-Mustansiriyah University, 10047 Bab Al Muadham, Baghdad, Iraq.

出版信息

Polymers (Basel). 2016 Apr 14;8(4):128. doi: 10.3390/polym8040128.

Abstract

The use of transparent polymers as an alternative to glass has become widespread. However, the direct exposure of these materials to climatic conditions of sunlight and heat decrease the lifetime cost of these products. The aim of this study was to minimize the harm caused by ultraviolet (UV) radiation exposure to transparent poly(methylmethacrylate) (PMMA), which usually leads to changes in the physical and chemical properties of these materials and reduced performance. This was achieved using environmentally friendly cellulose acetate butyrate (CAB). The optical, morphological, and thermal properties of CAB blended with transparent PMMA was studied using UV-VIS spectrophotometry, scanning electron microscopy, X-ray diffraction, dynamic mechanical analysis, and thermal gravimetric analysis. The results show that CAB was able to reduce the effects of UV radiation by making PMMA more transparent to UV light, thereby preventing the negative effects of trapped radiation within the compositional structure, while maintaining the amorphous structure of the blend. The results also show that CAB blended with PMMA led to some properties commensurate with the requirements of research in terms of a slight increase in the value of the modulus and the glass transition temperature for the PMMA/CAB blend.

摘要

使用透明聚合物替代玻璃已变得十分普遍。然而,这些材料直接暴露于阳光和热量的气候条件下会降低这些产品的使用寿命成本。本研究的目的是将紫外线(UV)辐射对透明聚甲基丙烯酸甲酯(PMMA)造成的损害降至最低,紫外线辐射通常会导致这些材料的物理和化学性质发生变化并降低性能。这是通过使用环保型醋酸丁酸纤维素(CAB)实现的。采用紫外可见分光光度法、扫描电子显微镜、X射线衍射、动态力学分析和热重分析研究了与透明PMMA共混的CAB的光学、形态和热性能。结果表明,CAB能够通过使PMMA对紫外线更透明来降低紫外线辐射的影响,从而防止在组成结构内捕获的辐射产生负面影响,同时保持共混物的非晶结构。结果还表明,与PMMA共混的CAB导致了一些与研究要求相称的性能,即PMMA/CAB共混物的模量值和玻璃化转变温度略有增加。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/4809/6432452/ae6ca24026bf/polymers-08-00128-g001a.jpg

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验