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基于磁控溅射的锂掺杂氧化锌薄膜的电阻开关特性

Resistive Switching Characteristics of Li-Doped ZnO Thin Films Based on Magnetron Sputtering.

作者信息

Zhao Xiaofeng, Li Yi, Ai Chunpeng, Wen Dianzhong

机构信息

Key Laboratory of Electronics Engineering, College of Heilongjiang Province, Heilongjiang University, Harbin 150080, China.

出版信息

Materials (Basel). 2019 Apr 18;12(8):1282. doi: 10.3390/ma12081282.

Abstract

A kind of devices Pt/Ag/ZnO:Li/Pt/Ti with high resistive switching behaviors were prepared on a SiO/Si substrate by using magnetron sputtering method and mask technology, composed of a bottom electrode (BE) of Pt/Ti, a resistive switching layer of ZnO:Li thin film and a top electrode (TE) of Pt/Ag. To determine the crystal lattice structure and the Li-doped concentration in the resulted ZnO thin films, X-ray diffraction (XRD) and X-ray photoelectron spectroscopy (XPS) tests were carried out. Resistive switching behaviors of the devices with different thicknesses of Li-doped ZnO thin films were studied at different set and reset voltages based on analog and digital resistive switching characteristics. At room temperature, the fabricated devices represent stable bipolar resistive switching behaviors with a low set voltage, a high switching current ratio and a long retention up to 10 s. In addition, the device can sustain an excellent endurance more than 10 cycles at an applied pulse voltage. The mechanism on how the thicknesses of the Li-doped ZnO thin films affect the resistive switching behaviors was investigated by installing conduction mechanism models. This study provides a new strategy for fabricating the resistive random access memory (ReRAM) device used in practice.

摘要

采用磁控溅射法和掩膜技术在SiO/Si衬底上制备了一种具有高阻变特性的Pt/Ag/ZnO:Li/Pt/Ti器件,该器件由Pt/Ti底电极(BE)、ZnO:Li薄膜电阻开关层和Pt/Ag顶电极(TE)组成。为了确定所得ZnO薄膜的晶格结构和Li掺杂浓度,进行了X射线衍射(XRD)和X射线光电子能谱(XPS)测试。基于模拟和数字电阻开关特性,研究了不同厚度Li掺杂ZnO薄膜器件在不同设置和重置电压下的电阻开关行为。在室温下,所制备的器件表现出稳定的双极电阻开关行为,具有低设置电压、高开关电流比和长达10 s的长保持时间。此外,该器件在施加脉冲电压时可维持超过10个周期的优异耐久性。通过建立传导机制模型研究了Li掺杂ZnO薄膜厚度对电阻开关行为的影响机制。本研究为制备实际应用的电阻随机存取存储器(ReRAM)器件提供了一种新策略。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/3d7f/6515171/e8544c08d4a5/materials-12-01282-g001.jpg

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