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用于水体砷去除的金属-有机骨架材料。

Metal-organic frameworks for aquatic arsenic removal.

机构信息

Beijing Research Institute of Chemical Industry, SINOPEC Group, Beijing, 100013, People's Republic of China.

Beijing Research Institute of Chemical Industry, SINOPEC Group, Beijing, 100013, People's Republic of China.

出版信息

Water Res. 2019 Jul 1;158:370-382. doi: 10.1016/j.watres.2019.04.043. Epub 2019 Apr 24.

Abstract

Effective remediation of arsenic contaminated water remains a critical task from the environmental perspective, owing to the harmful effects of arsenic on human health and the environment. Recently, highly porous metal-organic frameworks (MOFs) with excellent chemical stability and abundant functional groups represent a significant new addition to the area of capturing aquatic arsenic pollutants. This review focuses on the development of MOF-based materials for the efficient removal of toxic arsenic species from aqueous solutions. Aspects related to the materials' characteristics, application performance and interaction mechanisms are systematically studied, referencing the macroscopic experimental behaviors and microscopic spectroscopy analyses. The properties of various MOF-based materials are assessed and compared with those of other conventionally used materials. At last, insights and perspectives are suggested in terms of future research directions and development challenges. Overall, this class of materials demonstrates a promising potential for aquatic arsenic removal, and with a proper up-scaling development might it be used for practical applications in the near future.

摘要

有效修复受砷污染的水仍然是环境方面的一项关键任务,因为砷对人类健康和环境都有有害影响。最近,具有极好化学稳定性和丰富官能团的高多孔金属-有机骨架(MOFs)是捕获水相砷污染物领域的一个重要新增部分。本综述重点关注基于 MOF 的材料的开发,用于从水溶液中有效去除有毒砷物种。系统研究了与材料特性、应用性能和相互作用机制相关的方面,参考了宏观实验行为和微观光谱分析。评估了各种基于 MOF 的材料的性能,并与其他常用材料进行了比较。最后,就未来的研究方向和发展挑战提出了一些见解和观点。总的来说,这类材料在去除水相砷方面表现出了很有前景的潜力,如果进行适当的规模化开发,可能在不久的将来就能实际应用。

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