Sharma Anuj K, Pandey Ankit Kumar, Kaur Baljinder
Physics Division, Department of Applied Sciences, National Institute of Technology Delhi, Narela, Delhi-110040, India.
Materials (Basel). 2019 May 10;12(9):1542. doi: 10.3390/ma12091542.
Two-dimensional (2D) heterostructure materials show captivating properties for application in surface plasmon resonance (SPR) sensors. A fluoride fiber-based SPR sensor is proposed and simulated with the inclusion of a 2D heterostructure as the analyte interacting layer. The monolayers of two 2D heterostructures (BlueP/MoS and BlueP/WS, respectively) are considered in near infrared (NIR). In NIR, an HBL (62HfF-33BaF-5LaF) fluoride glass core and NaF clad are considered. The emphasis is placed on figure of merit (FOM) enhancement via optimization of radiation damping through simultaneous tuning of Ag thickness (d) and NIR wavelength (λ) at the Ag-2D heterostructure-analyte interfaces. Field distribution analysis is performed in order to understand the interaction of NIR signal with analyte at optimum radiation damping (ORD) condition. While the ORD leads to significantly larger FOM for both, the BlueP/MoS (FOM = 19179.69 RIU (RIU: refractive index unit) at d = 38.2 nm and λ = 813.4 nm)-based sensor shows massively larger FOM compared with the BlueP/WS (FOM = 7371.30 RIU at d = 38.2 nm and λ = 811.2 nm)-based sensor. The overall sensing performance was more methodically evaluated in terms of the low degree of photodamage of the analyte, low signal scattering, high power loss, and large field variation. The BlueP/MoS-based fiber SPR sensor under ORD conditions opens up new paths for biosensing with highly enhanced overall performance.
二维(2D)异质结构材料在表面等离子体共振(SPR)传感器应用中展现出迷人的特性。本文提出并模拟了一种基于氟化物光纤的SPR传感器,其中包含二维异质结构作为分析物相互作用层。考虑了两种二维异质结构(分别为BlueP/MoS和BlueP/WS)的单层结构在近红外(NIR)波段的情况。在近红外波段,采用了HBL(62HfF - 33BaF - 5LaF)氟化物玻璃芯和NaF包层。重点在于通过在Ag - 二维异质结构 - 分析物界面处同时调整Ag厚度(d)和近红外波长(λ)来优化辐射阻尼,从而提高品质因数(FOM)。进行了场分布分析,以了解在最佳辐射阻尼(ORD)条件下近红外信号与分析物的相互作用。虽然ORD对两者都导致了显著更大的FOM,但基于BlueP/MoS(在d = 38.2 nm和λ = 813.4 nm时FOM = 19179.69 RIU(RIU:折射率单位))的传感器相比基于BlueP/WS(在d = 38.2 nm和λ = 811.2 nm时FOM = 7371.30 RIU)的传感器显示出更大的FOM。从分析物的低光损伤程度、低信号散射、高功率损耗和大场变化等方面更系统地评估了整体传感性能。在ORD条件下基于BlueP/MoS的光纤SPR传感器为具有高度增强整体性能的生物传感开辟了新途径。