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来自. 的重排 clerodane 二萜

Rearranged clerodane diterpenoid from .

机构信息

National Center for Natural Products Research, School of Pharmacy, The University of Mississippi, University, MS, USA.

Department of Biomolecular Sciences, Division of Pharmacognosy, School of Pharmacy, The University of Mississippi, University, MS, USA.

出版信息

Nat Prod Res. 2021 Feb;35(3):369-376. doi: 10.1080/14786419.2019.1633648. Epub 2019 Jun 27.

Abstract

A new rearranged clerodane diterpenoid, tinocrispide was isolated from the stems of along with thirteen known compounds including eight clerodane diterpenoids. Among the known compounds baenzigeride A, (6 9 )vomifoliol and steponine are being reported for the first time from . Their structures were elucidated by 1 D and 2 D NMR and confirmed by HRESIMS. The C NMR data of borapetol A has been revised.

摘要

从锡纳克里普松()的茎中分离得到一个新的重排 clerodane 二萜,名为 tinocrispide,此外还分离得到了 13 种已知化合物,包括 8 种 clerodane 二萜。在已知化合物中,baenzigeride A、(6 9 )vomifoliol 和 steponine 是首次从锡纳克里普松中分离得到的。它们的结构通过 1D 和 2D NMR 确定,并通过 HRESIMS 确认。borapetol A 的 C NMR 数据已被修订。

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