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各类塑料袋中选定重金属和类金属含量的测定

Determination of the selected heavy metal and metalloid contents in various types of plastic bags.

作者信息

Alam Ohidul, Yang Li, Yanchun Xu

机构信息

UNEP_Tongji Institute of Environment for Sustainable Development (IESD), College of Environmental Science and Engineering, Tongji University, Shanghai, 200092 People's Republic of China.

出版信息

J Environ Health Sci Eng. 2019 Jan 26;17(1):161-170. doi: 10.1007/s40201-019-00337-2. eCollection 2019 Jun.

Abstract

The immense plastic bags (PBs) consumption is the potential threat for environment and public health due to discharging toxic pollutants (i.e., metals and metalloids) throughout its entire life cycle. The purpose of the study was to investigate the heavy metal (HM) contents in PE, HDPE, LDPE and PVC bags with several colors and applications. The HM contents in the PB were analyzed by ICP-OES after acid digestion. Results demonstrated that the HM contents in PB notably disagreed based on the used polymer types, colors and applications. The highest contents of Pb, Cr, Cd, As, Cu and Zn were 66, 75, 16, 28, 96 and 154 in mg/kg unit, respectively in PE bags; 71, 74, 34, 39, 430 and 212 in mg/kg unit, respectively in HDPE bags; 12, 74, 23, 43, 158 and 54 in mg/kg unit, respectively in LDPE bags; and 16, 23, 474, 12, 45 and 90 in mg/kg unit, respectively in PVC bags. Furthermore, 12 out of 36 PB samples were noticed to violate the standards (ISO 8124-3) in terms of Pb, Cr, Cd and As contents. So there is the potentiality of HM and metalloid pollution from discarded PB during treatment, recycling and disposal.

摘要

大量的塑料袋(PBs)消费对环境和公众健康构成潜在威胁,因为其在整个生命周期中都会排放有毒污染物(即金属和类金属)。本研究的目的是调查不同颜色和用途的聚乙烯(PE)、高密度聚乙烯(HDPE)、低密度聚乙烯(LDPE)和聚氯乙烯(PVC)袋中的重金属(HM)含量。通过酸消解后用ICP-OES分析塑料袋中的重金属含量。结果表明,根据所使用的聚合物类型、颜色和用途,塑料袋中的重金属含量存在显著差异。PE袋中铅、铬、镉、砷、铜和锌的最高含量分别为66、75、16、28、96和154毫克/千克;HDPE袋中分别为71、74、34、39、430和212毫克/千克;LDPE袋中分别为12、74、23、43、158和54毫克/千克;PVC袋中分别为16、23、474、12、45和90毫克/千克。此外,36个塑料袋样品中有12个在铅、铬、镉和砷含量方面不符合标准(ISO 8124-3)。因此,在废弃塑料袋的处理、回收和处置过程中,存在重金属和类金属污染的可能性。

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