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两种新的 3-己烯醇糖苷来自 的花萼。

Two new 3-hexenol glycosides from the calyces of var. .

机构信息

Research Centre for Good Practice in TCM Proessing Technology, Guangdong Pharmaceutical University, Guangzhou, PR China.

Key Laboratory of Jiangxi Province Natural Active Pharmaceutical Ingredients, College of Chemistry and Biology Engineering, Yichun University, Yichun, PR China.

出版信息

Nat Prod Res. 2021 Apr;35(8):1274-1280. doi: 10.1080/14786419.2019.1645657. Epub 2019 Jul 25.

Abstract

Two new hexenol glycosides, ()-hex-3-en-1-ol O--d-xylcopyranosyl-(1-6)- -d-glucopyranosyl-(1-2)--d-glucopyranoside () and ()-hex-3-en-1-ol O--d-xylcopyranosyl-(1-6)--d-glucopyranosyl-(1-2)--d-glucopyranoside (2), were isolated from the 50% ethanol elution of macroporous resin of var. . Their structures were established by detailed spectroscopic analysis, including extensive 2D-NMR data. This is the first time to report the () and () 3-hexenol glycosides from var. .

摘要

从 var. 的大孔树脂 50%乙醇洗脱部分分离得到两个新的己烯醇糖苷,()-己-3-烯-1-醇 O--d-木糖基-(1-6)- -d-吡喃葡萄糖基-(1-2)--d-吡喃葡萄糖苷 () 和()-己-3-烯-1-醇 O--d-木糖基-(1-6)--d-吡喃葡萄糖基-(1-2)--d-吡喃葡萄糖苷 (2)。通过详细的光谱分析,包括广泛的 2D-NMR 数据,确定了它们的结构。这是首次从 var. 中报道()和()3-己烯醇糖苷。

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