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花生壳作为用于锚定氧化铜的绿色生物分子载体:一种在超声辐射下绿色合成1,2,3-三唑的生物催化剂。

Peanut shell as a green biomolecule support for anchoring CuO: a biocatalyst for green synthesis of 1,2,3-triazoles under ultrasonic irradiation.

作者信息

Dolatkhah Zahra, Mohammadkhani Abolfazl, Javanshir Shahrzad, Bazgir Ayoob

机构信息

1Heterocyclic Chemistry Research Laboratory, Department of Chemistry, Iran University of Science and Technology, Tehran, 16846-13114 Iran.

2Department of Chemistry, Shahid Beheshti University, G.C, Tehran, 1983963113 Iran.

出版信息

BMC Chem. 2019 Jul 24;13(1):97. doi: 10.1186/s13065-019-0612-9. eCollection 2019 Dec.

DOI:10.1186/s13065-019-0612-9
PMID:31355370
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6659571/
Abstract

CuO supported on peanut shell (CuO@PS) was prepared by the reaction of copper acetate and peanut shell powder as a naturally available biopolymer support. The prepared catalyst was used as an efficient and reusable heterogeneous catalyst in the click reaction of benzyl halide or phenacyl bromides, acetylenes and sodium azide for the synthesis of potentially biologically active 1,2,3-triazoles under ultrasonic irradiation in EtOH-HO as green solvent.

摘要

以花生壳为载体负载氧化铜(CuO@PS)是通过醋酸铜与花生壳粉末反应制备的,花生壳粉末是一种天然可得的生物聚合物载体。所制备的催化剂在乙醇 - 水作为绿色溶剂的超声辐射下,用于苄基卤化物或苯甲酰溴、乙炔和叠氮化钠的点击反应中,作为一种高效且可重复使用的多相催化剂,用于合成具有潜在生物活性的1,2,3 - 三唑。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/958397b68192/13065_2019_612_Sch2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/8f4fd7c95893/13065_2019_612_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/af3ea9f24b8a/13065_2019_612_Sch1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/353a47b5da57/13065_2019_612_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/dd473a958ac6/13065_2019_612_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/ecb373ce97e3/13065_2019_612_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/e767eeffea06/13065_2019_612_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/0d7391686386/13065_2019_612_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/2679e02e0e3f/13065_2019_612_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/958397b68192/13065_2019_612_Sch2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/8f4fd7c95893/13065_2019_612_Fig1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/af3ea9f24b8a/13065_2019_612_Sch1_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/353a47b5da57/13065_2019_612_Fig2_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/dd473a958ac6/13065_2019_612_Fig3_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/ecb373ce97e3/13065_2019_612_Fig4_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/e767eeffea06/13065_2019_612_Fig5_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/0d7391686386/13065_2019_612_Fig6_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/2679e02e0e3f/13065_2019_612_Fig7_HTML.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/db29/6659571/958397b68192/13065_2019_612_Sch2_HTML.jpg

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